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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Plasma chemistry and plasma processing 15 (1995), S. 87-107 
    ISSN: 1572-8986
    Schlagwort(e): Air microwave plasma ; methane activation ; C2 hydrocarbon formation ; carbon monoxide formation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Technik allgemein
    Notizen: Abstract Activation of methane is carried out by means of an air microwave plasma (2.45 GHz). The experiments cover the absorbed microwave power range 350–650 W (20–50 W cm3 with 17–62%, of methane in the gas mixture, with pressures of 10–66 mbar and flow rates of 140‐700 ml min1. Methane, dioxygen, and dinitrogen consumptions as well as C2 hydrocarbons, carbon monoxide, and dihydrogen yields are analyzed hr gas chromatography. The distance of methane addition from the end of the discharge plays an important role in the composition and the concentration of the products obtained. This distance mainly determines the energy concentrated in the active species of the plasma when they react with methane. A kinetic mechanism jar the activation and decay of inethane and for the formation of C2 hydrocarbons and carbon monoxide is discussed based on the experimental results and kinetic data in the literature.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Plasma chemistry and plasma processing 18 (1998), S. 447-460 
    ISSN: 1572-8986
    Schlagwort(e): Nitrogen afterglow ; microwave discharge ; nitrogen atom concentration ; metastable nitrogen molecule concentration
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Technik allgemein
    Notizen: Abstract Measurements of nitrogen atom density, by means of NO chemical titration, along with an evaluation of the densities of some excited species N 2 (B, v=11), N 2 (B, v=2), N 2 (C, v=0), and N 2 + (B,v=0), by means of a spectroscopic study of some bands of dinitrogen, are achieved along the flowing afterglow of a dinitrogen microwave plasma (2450 MHz) for several pressures. The concentrations obtained are in the following range: [N]∼10 +15 , [N 2 (B, 2)]∼10 +9 –10 +10 , [N 2 (B, 11)]∼10 +8 –10 +9 , [N 2 (C, 0)]∼10 +6 –10 +7 , [N 2 + (B,0)]∼10 +6 -10 +8 (cm-3). From a kinetic study of the formation and decay of excited and charged species, an estimation of N 2 (A, v), N 2 (X, v, and N 2 + (X) densities can be derived: [N 2 (A, v)]∼10 +12 , [N 2 (X, v≥6)]∼10 +15 –10 +16 , [N 2 (X, v≥12)]∼10 +14 –10 +15 , [N 2 + (X)]∼10 +10 (cm -3 ).
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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