ISSN:
0887-624X
Keywords:
template polymer
;
dithizone
;
polystyrene
;
poly(methylethacrylate)
;
poly(vinyl chloride)
;
polycarbonate
;
copper
;
nickel
;
zinc
;
cobalt
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Metal ion specific template ligand sites were developed by physically immobilizing dithizone molecules oriented according to a particular complex geometry in various polymeric films. Four polymeric systems, polystyrene, poly(methyl methacrylate), poly(vinyl chloride), and polycarbonate, were used for making template sites for Cu2+, Ni2+, Zn2+, and Co2+ ions. A high degree of specificity could be achieved independent of stability constants, though about half of the ligand sites were unavailable to the metal ions. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 3729-3734, 1997
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
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