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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 56 (1999), S. 723-731 
    ISSN: 1572-8943
    Keywords: dielectric properties ; microwave heating ; thermal analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract This paper describes a new instrument for performing thermal analysis using microwaves both as a form of heating and as a novel means of detecting thermally induced transformations in materials. Results are presented for a selection of processes including decompositions, dehydrations and phase changes. The capability of the instrument to be coupled with ancillary techniques such as EGA is also demonstrated.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 56 (1999), S. 267-273 
    ISSN: 1572-8943
    Keywords: carbon activation ; SCTA ; TPO
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A constant rate method involving the control of the concentration of evolved CO2 at a constant level was used to study the air activation of pure and copper-doped carbon prepared from sodium carboxymethylcellulose. Whereas under a linear heating regime, both types of carbon reacted suddenly and quickly with O2, under constant rate conditions this violent reaction was avoided and oxidation proceeded steadily at a lower temperature until complete burn off of the carbon was achieved. The catalytic effect of the copper on carbon gasification was noted with lower reaction temperatures for both linear heating (380°C compared to 500°C) and for the constant rate experiments (320°C compared to 400°C).
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 56 (1999), S. 733-737 
    ISSN: 1572-8943
    Keywords: catalysis ; constant rate thermal analysis (CRTA) ; copper oxide ; temperature programmed reduction (TPR)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The reduction of bulk and supported copper oxide was investigated using Constant Rate-Temperature Programmed Reduction (CR-TPR) and conventional linear heating rate TPR. Linear heating profiles indicated that the reduction of supported samples was more facile than that of the bulk oxide. CRTA results revealed that both supported and bulk oxide samples were reduced via a mechanism involving a nucleation step and/or auto-catalysis. The increased reducibility of the supported samples is attributed to a higher dispersion which provides a larger reactive surface area and a high concentration of defects at which reduction is initiated.
    Type of Medium: Electronic Resource
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