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  • 1
    Electronic Resource
    Electronic Resource
    Polyferroorganosiloxanes as catalysts of oxidation processes (1996)
    Springer
    Russian chemical bulletin 45 (1996), S. 2870-2872 
    Details
    ISSN: 1573-9171
    Keywords: polyferroorganosiloxanes ; catalysts ; oxidation of hydrocarbons ; activation of hydrogen peroxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Polyferroorganosiloxanes were studied as catalysts for homogeneous oxidation of alkanes by hydrogen peroxide tinder mild conditions. In the oxidation of cyclohexane the catalysts are characterized by high efficiency (conversion of hydrogen peroxide is 25%) and stability Kip to 80 cycles per gat NJ The min product of the oxidation W do presence a 2,4,6-tri-tert-btitylphenol is cyclohexanol (tip to 35% per H2O2).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01430666
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Cobaltphenylsiloxane with ferromagnetic interaction (1996)
    Springer
    Russian chemical bulletin 45 (1996), S. 2026-2027 
    Details
    ISSN: 1573-9171
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01457804
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Magnetic isotope effect (1995)
    Springer
    Theoretical and experimental chemistry 31 (1995), S. 118-126 
    Details
    ISSN: 1573-935X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The electron spin selectivity of radical reactions is accompanied by nuclear spin selectivity, i.e., sorting of the isotopic nuclei relative to their magnetic moment. This property of spin-selective reactions produces separation of magnetic and nonmagnetic isotopes known as the magnetic isotope effect. The chemical physics of this phenomenon is examined along with the conditions and magnitude of its manifestation as well as the prospects for its use in theoretical and experimental chemistry.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00538783
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Experimental testing of molecular dynamic functions of pairs by the isotope selectivity of radical recombination (1995)
    Springer
    Russian chemical bulletin 44 (1995), S. 1571-1577 
    Details
    ISSN: 1573-9171
    Keywords: radical pair ; isotope effect
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A method for experimental testing of the molecular dynamic functionf(t), which describes the generation of reencounters in a dynamic pair of molecular particles, has been developed. The method is based on the analysis of isotope separation in spin selective reactions of a radical pair. Thef(t) function derived from the solution of the diffusion equation with physically rigorous initial and boundary conditions describes experimental results much better than the well-known Noyes function. Conditions that make it possible to increase the efficiency of isotope separation in spin selective reactions are formulated.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01151272
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  • 5
    Electronic Resource
    Electronic Resource
    Spin catalysis: dynamics of three-spin systems (1995)
    Springer
    Russian chemical bulletin 44 (1995), S. 1578-1584 
    Details
    ISSN: 1573-9171
    Keywords: catalysis, spin effects, kinetics ; radical reactions, quantum beats
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The kinetic theory of a new phenomenon, spin catalysis, has been developed. This phenomenon takes place in three-spin systems, when the third radical (or a paramagnetic ion) induces spin conversion in the pair, removes spin forbiddance, and thus changes the reactivity of the first two radicals. Kinetic equations for yields of spin catalyzed reactions have been derived. Conditions for spin catalysis, values of the catalytic effect, and the kinetic behavior are discussed. A new kind of quantum beats in chemical reactions is predicted.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01151273
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    Paper (German National Licenses)
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