ISSN:
1573-4803
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Maschinenbau
Notizen:
Abstract Solid solutions in the lead-based relaxor system Pb(Mg1/3Nb2/3)O3–PbTiO3 were modified by minor substitutions of Ba in the Pb-site of the perovskite lattice. The modified compositions were calcined at 830°C for 3 h to yield fine-grained, single-phase perovskite materials. A small amount of excess MgO(0.05 wt%), which mostly served as a sintering aid, was added to the calcined batches and the resulting mixtures were sintered at temperatures between 1150 and 1250°C for periods ranging from 3 to 5 h. The substitutions of BaO for PbO in the perovskite solid solution lattice caused a progressive lowering of the Curie point with increasing BaO content. On average, the Curie point decreased by about 10 °C for each mole of BaO substituted for PbO. Among the various Ba-substituted solid solutions studied, the one with a nominal composition Pb0.99Ba0.01[(Mg1/3Nb2/3)0.9Ti0.1]O3 which has a Curie point located near 28 °C, exhibited excellent dielectric properties. On sintering at 1250°C for 3 h, this composition yielded a density near 96% of the theoretical density. The peak dielectric constant of the composition at 1 KHz was slightly higher than 22000, and the corresponding tan δ value was 1.5% with a specific resistivity of 2.5×1012 Ω cm-1.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1018615421299
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