ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The femtosecond optical heterodyne detected optical Kerr effect/Raman-induced Kerr effect (OHD OKE/RIKE) is described in detail with emphasis on the utility for investigating the intermolecular spectra and dynamics of liquids. The femtosecond dynamics of the liquids CS2, benzene and CCI4 are addressed through a combination of conventional time-domain kinetic and Fourier-transform analyses, and the physical origin of the intermolecular intensity is addressed for each. The distinctions between the excitation mechanisms of the femtosecond OKE/RIKE and other continuous-wave and picosecond Raman techniques are described. The distinctions between the dephasing mechanisms of intramolecular and intermolecular vibrational modes are discussed.
Additional Material:
11 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250260712
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