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  • 1995-1999  (6)
  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 66 (1995), S. 4961-4966 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The discharge characteristics of an unbalanced magnetron sputtering device, equipped with a 100-mm-diam planar circular target and with two electromagnetic coils, have been analyzed in a range of operation pressures from 0.02 to 1 Pa. The variation of discharge extinction and ignition pressures and target voltage is presented as a function of the ratio of currents in the magnetron coils and discharge current. A maximum discharge current beyond which it is not possible to sustain the discharge at low pressures has been observed. This extinction current increases with operating pressures. An explanation for the effect is based on the loss of gas from the plasma due to gas heating with energetic sputtered particles and subsequent gas density rarefaction in the near target region. Higher pressure is thus necessary to keep constant gas density in the magnetron plasma when the discharge current is increased. The magnetic field configuration is presented for several values of the ratio of currents in the magnetron coils and correlated to the variation of discharge extinction and ignition pressures, extinction current, and target voltage. The low pressure operation of the magnetron strongly depends on optimization of the magnetic field shape on the sputtered target. The deposition rate of titanium films is a linear function of magnetron power up to 2.5 kW and does not depend on Ar pressure in the pressure range studied (0.08–0.6 Pa). © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Czechoslovak journal of physics 45 (1995), S. 249-261 
    ISSN: 1572-9486
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The electrical resistivity of as deposited polycrystalline copper thin films as a function of varying the process parameters has been investigated. Trying to minimize the resistivity of the copper thin films is important in the semiconductor industry, due to the fact that low resistivity copper can be employed to great advantage for new metallization schemes in advanced ultralarge scale integrated circuits. This paper presents the optimum choice of parameters that are necessary to achieve low resistivities of the thin films in reproducible experiments. All the depositions were performed using an unbalanced d.c. planar magnetron sputtering source (consisting of a circular copper target (98% purity, 0.01% Fe, 0.005% Ni, 0.005% Si) with a diameter of 100mm fitted with two electromagnets). The copper thin films were deposited onto glass substrates with argon being used as the sputtering gas. The resistivity was studied as a function of the pressure of the sputtering gas, the substrate bias, the substrate to target distance, the magnetron power, and the substrate temperature. It was found that depositions producing thin films with a resistivity of that approaching the bulk material (1.7×10−8Ωm) were obtained if the sputtering gas pressure was below 0.2 Pa. The effect of the substrate bias was insignificant at these pressures. The crystallographic structure of the copper thin films, determined by X-ray diffraction, is also reported.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Czechoslovak journal of physics 46 (1996), S. 353-368 
    ISSN: 1572-9486
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract This paper reports on d.c. sputtering of copper films using a cylindrical magnetron (CyM) with the discharge enhanced and/or ignited by a microwave plasma produced in an external magnetic fieldB e . The sputtering system was optimized with the aim to achieve high deposition rate of films at low argon pressures. It was achieved by enhancing the ionization degree of the discharge plasma by microwaves absorbed in the plasma and by the control of the distribution ofB e (z) along the device axis, i.e. by controlling the transport of the plasma to within a close vicinity of the sputtered target of the CyM. The optimized sputtering system can sputter films at low argon pressures from about 0.1 Pa down to 0.005 Pa and at quite large discharge currentsI d up to 1 A, i.e. at quite large deposition ratesa D of about several hunderds of nanometers per minute. The sputtering system operates at pressures lower than conventional magnetrons, i.e., under conditions when fast neutrals play a significant role. It opens the possibility to produce films of new properties. As an example, the microwave enhanced sputtering discharge was used to deposit Cu films. Resistivity and preferred crystal orientation of Cu films prepared under different argon pressures and at microwave powers ranging from about 100 W to 800 W is reported.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Czechoslovak journal of physics 48 (1998), S. 1209-1224 
    ISSN: 1572-9486
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The paper reviews a present state of the art in magnetron sputtering of alloy films. It shows that a mixing process, i.e. an addition of the second element into a base, one element film is, together with ion bombardment, the second dominant process which can be used to control the film structure. It describes general properties of one element films, binary metal alloy films and the films made of nitrides of binary metal alloys. A special attention is paid to formation of the nanocrystalline and nanocomposite films with a grain size of about 10nm and smaller, and of the high-temperature phases at low temperatures close to the room temperature. The alloy and alloy-based films with nanocrystalline structure represent, due to their novel structure and new physical properties, a new generation of materials. As an example, a new generation of hard coatings based on nanocomposite materials is given.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Czechoslovak journal of physics 48 (1998), S. 963-971 
    ISSN: 1572-9486
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We investigated the structure and composition of titanium carbide thin films deposited by the reactive magnetron sputter ion plating process as a function of deposition parameters. The films were sputtered onto unheated glass substrates by means of an unbalanced planar d.c. magnetron equipped with a titanium target using a mixture of argon and methane. The deposition parameters ranged from 0.05 Pa to 2 Pa for total working gas pressure p T, from 10% to 60% (volume) for relative methane concentration in the working gas mixture, from 45 mm to 85 mm for the substrate-to-target distance d s−t and from −50 V to −800 V for the substrate bias U S. It was found that the crystallinity of the thin films strongly decreases with increasing p T, d s−t and U S. The experiments described show the conditions necessary to obtain sputter-deposited nanocrystalline titanium carbide films.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Czechoslovak journal of physics 49 (1999), S. 359-372 
    ISSN: 1572-9486
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The paper reports on surface morphology, structure and microhardness of TiSi–N films formed by cosputtering from two target-facing unbalanced magnetrons, equipped with pure Ti and Si targets, on an unheated substrate rotating in front of both targets. The ratio Si/Ti in the TiSi–N film was achieved by modifying the magnitude of currents in the individual magnetrons and by the addition of nitrogen to the film. The rotation of the substrate has a strong effect on the film deposition rate and its morphology. The deposition rate is 3 times lower than that of the film deposited on a stationary substrate. The surface roughness of a polycrystalline Ti film deposited on the rotating substrate is considerably higher than that on a stationary substrate. On the contrary, the surface of an amorphous Si film is smooth and there is no difference between the roughness of Si films sputtered on stationary and on rotating substrates. The hardness of the film increases with increasing Si content and with the addition of nitrogen to the TiSi film. The Ti(26 at.%)Si(8.5 at.%)N(65 at.%)-film sputtered on an unheated rotating steel substrate, held at a floating potential, exhibited the best result with a hardness of 29 GPa.
    Type of Medium: Electronic Resource
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