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  • 1
    ISSN: 1075-4261
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Physics
    Notes: The study of the surface enhanced Raman spectroscopy (SERS) excitation profiles of 1,5-dimethylcytosine on metal colloids allows a more detailed determination of the behavior of the functional groups of this molecule in the adsorption process on the metal supports. Silver has shown its effectiveness and selectivity as a support for this technique from the point of view of its stability and capability to enhance the Raman signal coming from the adsorbate. The results are discussed in terms of the two well-known theories proposed up to now to explain the SERS phenomenon: electromagnetic and chemical (or charge transfer) models. © 1996 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biospectroscopy 3 (1997), S. 449-455 
    ISSN: 1075-4261
    Keywords: surface-enhanced Raman spectroscopy ; γ-aminobutyric acid ; Raman spectra ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Physics
    Notes: The surface-enhanced Raman spectroscopy (SERS) of γ-aminobutyric acid (GABA) adsorbed on silver colloids in H2O and D2O were recorded and analyzed. When the concentration is greater than 10-3 M, the adsorbed species is the anionic form of the amino acid that interacts with the surface through both functional groups. According to the vibrational interpretation of the spectra, it is assumed that at concentrations in the order of or less than 10-3 M, GABA undergoes chemical transformations, which increase upon dilution, and spectra are recorded that are the result of the competitive adsorption between the amino acid in its anionic form and the products resulting from the chemical transformations. © 1997 John Wiley & Sons, Inc. Biospectroscopy 3: 449-455, 1997
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 26 (1995), S. 637-641 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: SERS spectra of succinic and oxalic acids on silver sols have been revised. For the latter molecule the vibrational spectrum has been assigned on the basis of AM1 and 3-21G ab initio force field calculations. Also, SERS of the malonate ion is presented for the first time, showing some general characteristics similar to the aforementioned. The results have been analysed together, and a model is proposed in which the interaction with the surface is through one carboxylate group in the case of oxalic acid and through both carboxylate groups in the case of malonic and succinic acids.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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