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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 49 (1993), S. 487-499 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In this article, symmetrical, narrow distribution P (S-b-MMA) block copolymers are characterized rheologically, using a dynamic spectrometer and a stress rheometer. The shear induced morphology changes are investigated by off-line electron microscopy and SAXS. We tried to correlate the results of dynamics and long-time creep experiments with morphological and rheological features. Summarizing, one can point out that the examined block copolymers reveal the well-known low frequency behavior of phase separated blends. Additionally, we observed a significant shear influence on the morphology, i.e. a shear induced structuring and alignment of lamellae. This considerable change in morphology is also reflected by the characteristic rheological properties (retardation time, yield stress). Therefore, problems concerning the validity range of linear viscoelastic behavior arise, which are discussed in brief. © 1993 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Advances in Polymer Technology 8 (1988), S. 17-26 
    ISSN: 0730-6679
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The production of automotive exterior body panels in the PUR-RRIM process is a comparatively new technology that provides a great potential for further improvements and makes it possible to produce plastic components for the automotive industry that, at relatively thin wall thicknesses, meet maximum requirements in regard to part geometrydimensional stabilitythe high industrial standards valid in the automotive industrysurface quality (avoidance of sink marks, pores, etc.)durable fastening For a better acceptance of RRIM moldings, cost reductions in the production process are necessary which, in turn, require noticeable progress in the material and process development. Due to the improvements made in the field of both raw materials and production units, the PUR-RRIM process has, in the last few years, become interesting also for high-volume production. A handicap in this connection is that the development of the RRIM process is, to a large extent, based on the practical experience of a few experts. For its use in high-volume production it is, however, inevitable to have at hand through scientific data on material, design, process and resulting correlations. It is the objective of the Institute for Polymer Testing and Polymer Science in Stuttgart to help establish these data and, through close contacts to the industry, make them usable in practice.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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