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Alkyl nitrate formation from the reaction of a series of branched RO2 radicals with NO as a function of temperature and pressure (1987)

Atkinson, Roger ; Aschmann, Sara M. ; Winer, Arthur M.

Springer

Journal of atmospheric chemistry 5 (1987), S. 91-102

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Details

ISSN: 1573-0662

Schlagwort(e): Alkane ; alkyl nitrate ; tropospheric chemistry ; nitrogen oxides ; alkyl peroxy radical

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie , Geologie und Paläontologie

Notizen: Abstract Alkyl nitrate yields from the NO x photooxidations of neopentane, 2-methylbutane and 3-methylpentane have been determined over the temperature and pressure ranges 281–323 K and 54–740 torr, respectively. The formation of the alkyl nitrates is attributed to the reaction pathway (1b) $${\text{RO}}_{\text{2}} + {\text{NO}}^{{\text{ }}\underrightarrow {\text{M}}} {\text{ RONO}}_{\text{2}}$$ and rate constant ratios k 1b/(k 1a+k 1b) are estimated, where (1a) is the reaction pathway (1a) $${\text{RO}}_{\text{2}} + {\text{NO}} \to {\text{RONO}}_{\text{2}} .$$ A method for estimating this rate constant ratio for primary, secondary and tertiary alkyl peroxy radicals is presented.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00192505

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