ISSN:
0009-2940
Keywords:
Thioketenes
;
Flash-vacuum pyrolysis
;
Diels-Alder reaction
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Flash-vacuum pyrolysis of 2,4-bis(dichloromethylene)-1,3-dithietane (1) at 820°C furnishes dichlorothioketene (2a) which may be trapped with cyclopentadiene (3) in a [4+2] cycloaddition. The constitution 4a of the product is confirmed by an X-ray structural analysis of the related cycloadduct 4b.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240626
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