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  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 20 (1993), S. 949-954 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Transmission Móssbauer spectra of binary coprecipitated nickel(II)-iron(III) hydroxides (molar ratios 9:1 and 4:1) are analysed and compared with the results of AES analyses of their surface composition. A correlation between the data of the above techniques has been noted, indicating a redistribution of the components (i.e. Ni and Fe) in the surface layers, the latter being enriched with iron(III) as compared to the bulk. The results obtained are in good agreement with an excellent electrocatalytic activity of composite Ni-Fe hydroxide systems towards anodic oxygen evolution in alkaline electrolytes, taking into account a distinctly exhibited ‘surface’ electrocatalytic effect of ferric species on the nickel hydroxide electrode in the anodic oxygen evolution process revealed previously. Transmission Móssbauer spectroscopy has been shown to be a highly effective probe sensitive both to various bulk and surface effects related to the solid phases studied.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1520-4804
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 2918-2923 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A quantum molecular dynamics study of the interface formation of the Al/GaAs(110) and In/GaAs(110) interfaces has been performed. It is found that, at very low coverages, both Al and In atoms chemisorb on threefold coordinated sites, bonded to two As atoms and one Ga atom. The metal atoms attract each other on the GaAs surface and tend to form islands. The electronic structure for one monolayer is found to be semiconducting for both In and Al. The results presented here are consistent with the temperature-dependent evolution of Fermi level from the very low metal coverage limit to the overlayer limit for the deposition of In and Al on GaAs(110).
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 100 (1994), S. 2437-2448 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The combination of concepts of two-dimensional (2D) spectroscopy with the well-known field step electron–electron double resonance (ELDOR) method offers a practical route to recording 2D ELDOR spectra covering the full spectral range needed for electron paramagnetic resonance (EPR) of nitroxide spin labels in the solid state. The 2D ELDOR pattern provides information about molecular reorientation measured in real time, the anisotropies of electron phase, and electron spin-lattice relaxation as well as nuclear spin-lattice relaxation all of which are connected with the detailed geometry of the molecular reorientation. Thus, in 2D ELDOR the same electron spin probes the motional behavior over a wide range of correlation times from 10−4 to 10−12 s. An efficient algorithm for simulating 2D ELDOR spectra is derived, based on analytical solutions of the spin relaxation behavior for small-angle fluctuations and offers a means of quantitatively analyzing experimental data. As an example, the motion of nitroxide spin labels in a liquid-crystalline side-group polymer well below its glass transition is determined as a β-relaxation process with a mean angular amplitude of 5° and a distribution of correlation times with a mean correlation time of 0.9×10−10 s and a width of 2.5 decades.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 8842-8859 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Numerical evidence is reported of the quasiregular power spectra in the strongly chaotic system of coupled Morse and harmonic oscillators with the 1:2 frequency ratio. The spectra are shown to consist of a "regular'' part, characterized by sharp peaks and a chaotic one which resembles a smooth chaotic background. The regular part does not seem to be related to the visible islands of stable motion as is the case of the standard map. The observed regularity of the spectra is shown to be associated with the repeated trapping of the chaotic trajectory by the localized regions of marginal stability. The appearance of such regions is the direct consequence of the global tangent bifurcations near the borderline of the system. The analysis of the spectra of local Lyapunov exponents and periodic orbits analysis seem to account for the most important qualitative features of the underlying chaotic dynamics. In particular we show that a relatively small number of low-period saddle-center pairs born in tangent bifurcations is sufficient to characterize marginally stable sets and to determine their recurrence properties as well.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Psychophysiology 12 (1975), S. 0 
    ISSN: 1469-8986
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine , Psychology
    Notes: Twenty-eight normal adults participated in an experimental test of two assumptions underlying the use of electromyographic (EMG) biofeedback as a general relaxation training technique: (1) that trained EMG reduction in one muscle generalizes to untrained muscles; and (2) that subjective feelings of relaxation are related to EMG reduction. An experimental group received 5 sessions, during the middle 3 of which EMG biofeedback training was offered on the frontalis muscle. Throughout all sessions, EMG recordings were also taken from the forearm and lower leg, and ratings of subjective relaxation feelings were obtained at regular intervals. A control group, matched with the experimental group on baseline frontalis EMG, received 5 similar sessions without feedback. Employing a maximum p of .05, the results revealed no evidence of generalization of EMG reduction from the frontalis to the untrained sites, nor any tendency for successful frontalis EMG reduction to result in increased feelings of relaxation beyond what was obtainable from relaxing without the benefit of training. The results were interpreted as suggesting that EMG biofeedback cannot yet be accepted as a viable general relaxation training technique.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Psychophysiology 14 (1977), S. 0 
    ISSN: 1469-8986
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine , Psychology
    Notes: Twenty-two normal adults participated in an electromyographic (EMG) biofeedback experiment designed to test if the feedback stimulus is necessary in obtaining EMG reductions during typical laboratory procedures, and if prior training on one muscle facilitates the training of a second muscle. One group of subjects received forearm feedback training followed by frontalis training. A second group received training in the reverse order. Two control groups relaxed first on their own followed by either forearm or frontalis training. Attention was directed toward motivating control subjects to perform maximally during relaxation without feedback. Heart and respiration rates and skin conductance and temperature were also recorded. Both trained and untrained subjects produced significant EMG reductions but did not differ from each other; nor did a transfer of training effect emerge. No differences resulted between feedback and non-feedback conditions for the other physiological measures or for changes in state anxiety. These data compromise somewhat the previous demonstrations of EMG biofeedback “learning,” and are unsupportive of EMG biofeedback as a general relaxation training technique.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Psychophysiology 12 (1975), S. 0 
    ISSN: 1469-8986
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine , Psychology
    Notes: This study compared the efficacy of auditory and visual feedback in electromyographic (EMG) biofeedback assisted relaxation training of the frontalis muscle.Twenty-eight subjects, divided into 4 groups matched on baseline frontalis EMG levels and trait anxiety, received 7 training sessions each under one of the following conditions: (1) auditory feedback-eyes closed; (2) auditory feedback-eyes open; (3) visual feedback; or (4) no feedback-eyes closed. The group who received auditory feedback with the eyes closed manifested significant lowering of EMG over session compared to no significant reduction in EMG for the other three groups. EMG changes failed to correlate significantly with changes in self reports of subjective relaxation derived from pre-to-post session state anxiety test data. The possibility that the ineffectiveness of visual feedback in this study may be specific to the frontalis muscle was discussed and the need for further research in several areas was stressed.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry 46 (1954), S. 1977-1985 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 6 (1994), S. 187-198 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A dissipation-modified Boussinesq-like system of equations governing three-dimensional long wavelength Marangoni–Bénard oscillatory convection in a shallow layer heated from the air side is presented. Solitary waves and their oblique and head-on interactions are considered, thus leading to results that compare well with available experimental data.
    Type of Medium: Electronic Resource
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