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  • 1
    Electronic Resource
    Electronic Resource
    Mechanistic and Preparative Aspects of Vinyl Cation Chemistry (1978)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 17 (1978), S. 333-341 
    Details
    ISSN: 0570-0833
    Keywords: Vinyl cations ; Carbocations ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Compelling evidence for the intermediacy of vinyl cations has accumulated in recent years. Vinyl cations can be generated by electrophilic additions to alkynes and allenes, and on participation of such functions in solvolysis reactions. Heterolysis of vinyl compounds likewise affords vinyl cations. Syntheses of substituted indenes, cyclobutanones, and cyclopropyl ketones illustrate preparative applications.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.197803331
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