Bibliothek

feed icon rss

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
Filter
  • 1990-1994  (2)
  • 1975-1979
  • Chemical Engineering  (2)
Materialart
Erscheinungszeitraum
Jahr
  • 1
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 773-776 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The melt rheology of phase separated blends of two thermotropic liquid crystalline polymers (LCPs) have been studied. The two components are a random copolyesters consisting of 73 mol% 4-hydrobenzoic acid (HBA) and 27 mol% 6-hydroxy-2-napthoic acid (Vectra A900 of Hoechst Celanese Corp.) and a poly(ethylene terephalate-co-4-oxybenzoate) containing 60 mol% HBA units (PET/60HBA of Eastman Kodak Corp.). Most striking is the effect of adding 10% PET/60HBA to Vectra A900: The viscosity at 290°C drops by a factor of 4 and the terminal zone of the relaxation time spectrum is shifted to much shorter times. This is an interesting effect that could be used for LCP processing even if its origin is not yet understood. Differential scanning calorimetry measurements support the hypothesis that the blend is phase separated and that no transestification reaction occurs during the experiments.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 408-415 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A numerical method has been developed that takes the streamline finite difference method for modeling fully developed multilayer polymer flows and adds to it a simple means of accounting for nonisothermal conditions. In industrial practice, temperature control is often used to match material viscosities and, thereby, to avoid flow instabilities. By numerically calculating both viscosity ratios and normal stress difference ratios, the numerical method allows one to judge the relative stability of different flows and to choose an intelligent set of experiments when designing a coextrusion process. The algorithm has been successfully tested for a number of polymer melt constitutive equations in flows where the viscosity jumps no more than two orders of magnitude between fluids. Results for a rheologically well characterized polystyrene low-density polyethylene system and for an industrially interesting high-density polyethylene/Ultem system show that the common practice of matching zero-shear viscosities is overly simplistic when interface shear rate, conduction, normal stress, and flow rate effects are taken into account.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...