ISSN:
1434-6079
Keywords:
31.10.+z
;
36.40.+d
;
33.45.+x
;
33.60.-q
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract We discuss the electronic structure, bonding and physical properties of the gold cluster compound Au55(PPh3)12Cl6. Results from our experimental measurements, including EXAFS, specific heat, Mössbauer, UV-visible and photoelectron spectroscopy, are combined with those of other work to form a consistent physical picture of the system. The bonding in Au55(PPh3)12Cl6 is much more delocalised and non-directional than in smaller gold cluster molecules. The Au55 cluster exhibits a substantial degree of metallic bonding, while displaying some of the characteristics of a discrete energy level spectrum.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01429131
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