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  • 1990-1994  (3)
  • 1970-1974  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 96 (1992), S. 3319-3329 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Ultraviolet photoelectron spectra (UPS) were recorded for mass-selected negative clusters of copper (1–411 atoms), silver (1–60 atoms), and gold (1–233 atoms), using photodetachment lasers at 6.4 and 7.9 eV photon energy. The results provide a direct estimate of the vertical electron affinity (EA) of these clusters and information on the evolution of the d bands of copper and gold as a function of cluster size. The large even/odd alternation of EA in small clusters of these metals in earlier work is found to largely disappear as the cluster size exceeds 40 atoms. The ellipsoidal shell model is shown to be consistent with the observed EA behavior of all three metals, the predicted spherical shell closing at cluster 58 being evident for silver and gold. The UPS data show a smooth evolution of the d band toward that of the bulk metal.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 7515-7518 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Spectral experiments on mass-selected negative cluster ions of gold and silver were performed in the wavelength range near the threshold for one-photon photodetachment of the extra electron. The Au−6 cluster ion displayed a uniquely well resolved spectrum consisting of a progression in a single vibrational mode. Details of this threshold photodetachment spectrum and the associated photoelectron energy distribution suggest an explanation based on autodetachment from totally symmetric vibrational levels of very weakly bound excited electronic state (bound by image charge forces) of the Au−6 cluster in the form of a planar, six-fold symmetric, gold ring.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 47 (1991), S. 553-559 
    ISSN: 1420-9071
    Keywords: Sulphate-reducing bacteria ; corrosion ; nuclear waste
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Experiments are described which investigate corrosion of forged 0.2% carbon steel in the presence of sulphate reducing bacteria (SRB). Cultures of a thermophilic bacteriumDesulfotomaculum nigrificans were mixed with bentonite and synthetic groundwater to simulate a bacteria-contamined backfill, and placed in contact with carbon steel disc specimens in perspex cells at 50°C under anaerobic conditions. The rates of corrosion were monitored by electrochemical techniques, together with changes in near field redox potential. After 340 days the nature and extent of any corrosion was measured and the SRB content of the bentonite determined. Recovery of relatively large numbers of bacteria after about one year incubation in an alkaline (pH 9.5) medium confirmed the pH tolerance of the strain. Enhanced corrosion (three times the rate of the control) occurred in at least two of the five cells that contained SRB despite the nutritionally poor environment which existed in the bentonite gel.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of low temperature physics 2 (1970), S. 389-402 
    ISSN: 1573-7357
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The onset of sonically induced cavitation in liquid helium at frequencies between 30 and 40 kHz has been studied. In helium II, two types of cavitation activity were identified: acoustic cavitation whose characteristic noise can be detected, and visible cavitation in which vaporous cavities grow to visible size. The onset of acoustic cavitation is statistical in nature with increasing event rates as the sound pressure amplitude is increased and whose threshold depends on the waiting time at that particular amplitude. The acoustic threshold sound pressure amplitude in helium II between 1.8° K andT λ was found to lie within 0.15 mb of 0.3 mb, the variation of ±0.15 mb occurring from one determination to another, whereas the sound pressure amplitude corresponding to the visible threshold was about a hundred times larger. These two distinct types of sonically induced cavitation appear to be unique to liquid helium. However, aboveT λ the two thresholds were found to coincide at a sound pressure amplitude within 0.4 mb of 0.8 mb. The characteristics of the onset of acoustic cavitation were found to be independent of applied static pressure of up to 1.5 atm above and belowT λ and in helium II they were unaffected by filtering, heat flushing, or rotating the liquid. The results suggest that liquid helium is nucleated by random events initiated by the ambient cosmic radiation or by vortices generated in the liquid, and they imply that at ultrasonic frequencies this liquid cannot withstand a tensile stress and behaves in this respect like water saturated with gas and containing dust motes. Attempts to determine the onset of acoustic cavitation by scattering light off the bubbles or by detecting sonoluminescence were not successful: The upper limit to the size of these bubbles was shown to be about 30 µm and the intensity of any sonoluminescence must have been less than 10−4 of that from cavitating water. The possibilities of exploiting the two types of cavitation activity in liquid helium in the construction of a posttriggerable ultrasonic bubble chamber for visualizing the tracks of ionizing particles are discussed, as are the theoretical background and future development of the work presented in this paper.
    Type of Medium: Electronic Resource
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