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  • 1
    ISSN: 1042-7147
    Keywords: Unidirectional composites ; Interlaminar shear strength ; Longitudinal and transverse mechanical properties ; Reversible energy of adhesion ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The aim of the last part of this general study is to analyze the influence of the interfacial properties and, more precisely, the adhesion energy, between carbon fibers and PEEK on the final performance of unidirectional composites. A set of mechanical properties, i.e. interlaminar shear strength, longitudinal tensile and compressive and transverse tensile properties, of different unidirectional laminates with the same content (60% by volume) of carbon fibers is determined. It is first shown that the interlaminar shear strength is constant, whatever the type of materials. Therefore, this test is not appropriate to characterize the strength of the fiber-matrix interface in PEEK-based composites. On the contrary, in agreement with previous work on other systems, it appears that the ultimate properties (longitudinal tensile and compressive as well as transverse tensile strengths and strains) of the laminates increase with the interfacial adhesion energy, whereas the stiffness of these composites remains unaffected in all cases.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 64 (1992), S. 865-865 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Diffusionskoeffizienten von Monomeren (Vinylacetat, Styren) in Poly(vinylacetat)-Filmen wurden mit Hilfe der abgeschwächten Infrarot-Totalreflexions-Spektroskopie und gravimetrisch bestimmt. Die dabei erhaltenen Diffusionskoeffizienten sind nahezu identisch. Das wird als ein Hinweis darauf gewertet, daß die molekularen Vorgänge der Diffusion von kleinen Molekülen im Volumen und in Oberflächenschichten des Polymer in ähnlicher Weise verlaufen.
    Notes: The diffusion coefficients of monomers (vinyl acetate, styrene) within poly(vinyl acetate) films were measured by means of infrared attenuated total reflection spectroscopy and gravimetry. The diffusion coefficients obtained by the two methods are almost identical. This is interpreted as an indication that the molecular processes of diffusion of small molecules in bulk and in surface layer regions of the polymer take place in a similar manner.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 24 (1957), S. 291-292 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 41 (1959), S. 415-423 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Diffusion and solubility coefficients for several gases in undrawn and drawn films of four high polymers (polyvinyl butyral, nylon 66, polyethylene, and polypropylene) are reported as functions of temperature. In general, the diffusion, solubility, and permeability coefficients of the semicrystalline polymers investigated changed on drawing. The magnitude and direction of such changes depended on the penetrant used and on the experimental temperature. The molecular orientation introduced by stretching in one direction had little or no effect on the diffusion properties of the amorphous polyvinyl butyral. With the other polymers, the changes in void content on cold drawing were usually found to be associated with changes of the opposite sign in the activation energy of diffusion, in consequence of the relatively weak temperature dependence of diffusion in the gas phase. The process of solution of low molecular weight gases in high polymers was found to be more exothermic for those samples which had a comparatively low void content (i.e., drawn polyethylene, undrawn nylon 66, and undrawn polypropylene, as compared, respectively, to undrawn polyethylene, drawn nylon 66, and drawn polypropylene). Possible explanations for this result are given.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 41 (1959), S. 403-414 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Diffusion and solubility coefficient were determined by the time-lag method for ethane and some other low hydrocarbons in various polyethylenes. The time-lag method was modified to give significant savings in experimental time and increased precision. Diffusion and solubility coefficients both depend quite strongly on the density and hence on the crystallinity. There is no discernible effect of weight-average molecular weight, and the effect of polymer chain side branches is found to be small or absent. The thermal and fabrication history of the samples has some effect on the diffusion coefficients. The character of the amorphous regions appears to be independent of the overall density as far as the diffusion process is concerned. The effect of the size of the penetrant molecule is analogous to that found by other authors for rubbers. The findings support the view that small molecule diffusion in polymers requires only short range motions, whereas other mechanisms, such as the dissolution of entanglements, are known to be of importance in melt flow and polymer self-diffusion.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 17 (1992), S. 232-236 
    ISSN: 0721-3115
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of radial confinement of explosive on the impulse delivered to an explosively driven circular plate was investigated numerically. The results are applicable to the design of explosively formed penetrators. Aluminum radial confinement and additional radial explosive were investigated as means of increasing the impulse delivered to the plate. The radial thicknesses were varied from 0% to 10% of the explosive charge diameter with copper plates having thicknesses of 2%, 5% and 8% of the explosive charge diameter.Results show the use of radial confinement to be more effective with thicker plates. The increase in impulse provided by aluminum confinement was as great as 18% with an 8% charge diameter thick plate, compared to 12% with a 2% charge diameter thick plate. Regardless of the plate thickness, additional radial explosive can be more effective than aluminum radial confinement in increasing the impulse. For example a 10% charge diameter thickness of explosive increases the impulse by up to 28%, compared to 18% for the same thickness of aluminum. The results do not exhibit dependence on the method of detonation, nor on the length of the explosive charge.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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