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  • 1990-1994  (3)
  • Polymer and Materials Science  (3)
  • (Human)
  • Cytochrome P450
  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 29 (1990), S. 335-346 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Small-angle neutron scattering (SANS) was used to study the structure of protein/sodium dodecylsulfate complexes. Two water soluble proteins, bovine serum albumin (BSA) and ovalbumin (OVA), were used. The protein concentration was kept constant at 1 wt %, and protein/detergent wt ratio varied between 1/1, 1/1.5, 1/2 and 1/3. Absolute intensities of SANS distributions were analyzed by a fractal model. Analyses of large Q portions of SANS distributions established that sodium dodecylsulfate (SDS) molecules bound to a protein/SDS complex form micelle-like clusters. On the other hand, analyses of small Q portions of SANS distributions clearly showed that the arrangement of micelle-like clusters resembles a fractal packing of spheres. We showed that a protein/SDS complex can be characterized by four parameters extracted from the scattering experiment, namely, the average micelle size and its aggregation number, the fractal dimension characterizing the conformation of the micellar chains, the correlation length giving the extent of the unfolded polypeptide chains, and the numbers of micelle-like clusters in the complex.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 32 (1994), S. 1791-1798 
    ISSN: 0887-6266
    Keywords: alternating poly(ethylene-propylene) (hydrogenated polyisoprene) melts ; pressure-volume-temperature (P-V-T) properties ; density ; specific volume ; equations of state ; Flory-Orwoll-Vrij (FOV) ; Modified Cell Model (MCM) ; Sanchez-Lacombe (SL) ; Statistical Associating Fluid Theory (SAFT) ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The pressure-volume-temperature (P-V-T) properties of monodisperse alternating poly(ethylene-propylene) (hydrogenated polyisoprene) melts of varying molecular weights are measured at 0.1 MPa 〈 P 〈 200.1 MPa, and 290 K 〈 T 〈 510 K in a dilatometer-type apparatus. The Flory-Orwoll-Vrij (FOV), Modified Cell Model (MCM), Sanchez-Lacombe (SL), and the Statistical Associating Fluid Theory (SAFT) equations of state are found to correlate the experimental data with excellent accuracy, except either at low pressures and high temperatures, or at high pressures and low temperatures. On average, MCM and SAFT fit the data slightly better than FOV and SL. The equation-of-state parameters are found to be independent of molecular weight, especially for SAFT, as required by the theory. © 1994 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Advances in Polymer Technology 12 (1993), S. 361-378 
    ISSN: 0730-6679
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The Intelligent Processing of Materials (IMP) concept has been applied to the calendering process with the goal of improving shape quality and process efficiency. All four basic features of the IPM, including modeling, data processing, sensing, and controlling, are considered. In the process modeling, bending and thermal models are developed. With these models, the relationship between the process parameters and quality of the calendered sheets has been established. A material data bank has been established to couple with the process modeling and real-time sensing data. In sensing, ultrasonic and temperature sensors have been implemented to measure critical quality and process parameters in situ. The sensing data have been used not only to verify the modeling prediction but also to establish information needed to diagnose the causes of the layflat problem. Based on the model prediction as well as sensing information, a better control system to alleviate layflatness problems has been developed. Finally, a control strategy for future improvement of the calendering system is proposed. © 1993 by John Wiley & Sons, Inc.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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