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  • 1
    ISSN: 1420-9071
    Keywords: Sex pheromone ; male secretion ; chemical analysis ; (Z,Z) 6,9 heneicosadiene ; (Z,Z,Z) 3,6,9 heneicosatriene ; (Z,Z)-3,6-cis-9S,10R-epoxyheneicosadiene ; Mocis megas
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Pheromonal secretions produced by females and males of the noctuid moth,Mocis megas (Guénée) have been analyzed by gas chromatography and mass spectrometry (EI (electron impact) and CI (chemical ionization)). The female sex pheromone was a blend of (Z,Z,Z) 3,6,9 heneicosatriene (55%) and (Z,Z) 3,6-cis-9S, 10R-epoxyheneicosadiene (45%). Male secretion produced at the level of a prothoracic organ was a blend of two unsaturated major hydrocarbons: (Z,Z) 6,9 heneicosadiene, (64%) and (Z,Z,Z) 3,6,9 heneicosatriene (24%) and C19, C20 and C22 homologues (total ratio 12%), as minor components. The trienic hydrocarbon was present in both sexes. The behavioral role of this male secretion has not yet been elucidated.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 25 (1990), S. 49-52 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A recent reinvestigation of the reactivity of NO+ towards straight-chain monoolefinic compounds revealed that the characteristic acylium ions, previously reported for alkenyl acetates and related compounds, could also be obtained from alkenes and alkenoic acids (or esters). In this study, the influence of the sample pressure and that of NO on the production of the acylium ions was investigated, leading to disappearance graphs indicative of a strong dependence on these experimental factors. This gives a further explanation for previous apparent discrepancies in the literature and the optimum conditions of use for double-bond location in a variety of substituted or unsubstituted monoolefins.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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