ISSN:
0009-2940
Keywords:
1,3,2-Benzodioxaborole, (2-dimethylgermyl)-
;
(Chloro-hexamethyltrigermyl)tetramethylpiperidino-borane
;
1,2,3,4-Trigermaborolane derivatives
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Contributions to the Chemistry of Boron, 211[1]. - On the Formation of Boron-Germanium Bonds with Dimethylgermylene2-(Dimethylgermyl)-1,3,2-benzodioxaborole (3) is formed by insertion of dimethylgermylene into the BH bond of catechol borane (2). According to the same principle, the trigermylborane 5 is obtained by insertion of three Me2Ge units into the BCl bond of chloro(2,2,6,6-tetramethylpiperidino)borane (4). Me2Ge reacts with 9-fluorenylidene(tetramethylpiperidino)-borane 8 to yield the trigermaborolane 10, which is characterized by an X-ray structure analysis.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250217
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