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Ligandenaustausch in Alkoxo/Halogenostiban-Systemen (1993)

Greiner, R. ; Detampel, B. ; Schmidt, A.

Springer

Monatshefte für Chemie 124 (1993), S. 827-837

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ISSN: 1434-4475

Keywords: Alkoxo/Halogenostibanes ; Ebullioscope ; Ligand exchange

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Summary In Sb(OR)3/SbHal 3 systems (R=Et, Pr, i Pr, Bu, i Bu, neo Pent; Hal=Cl, Br) a rapid exchange of ligands takes place. It is shown by ebullioscopic data that there is a random distribution in a system containing 7 different particles. The mixed alkoxohalogenostibanes are associated. The total association is estimated comparing the averaged experimental and statistical molecular masses. An ebullioscope of high precision is described.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00816405

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