ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The gas-phase, ion molecule reaction between C3O2+. and C3O2 has been studied by both double-focusing and ion trap mass spectrometry, rationalized by the formation of a dimeric, odd electron cation [C6O4]+. which decomposes extensively through sequential CO losses giving rise to [C5O3]+. and [C4O2]+. ions. The thermodynamics of this process have been investigated by means of ab initio calculation performed on the above species using different basis sets (STO-3G, 3-21G and 6-31G*).
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210291005
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