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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 44 (1994), S. 387-391 
    ISSN: 0006-3592
    Keywords: diffusion limitation ; layer thickness ; sulfate reducing bacteria ; methanogenic bacteria ; competition ; UASB granule ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The role of mass transfer limitation of sulfate as a factor governing the competition between sulfate reducing and methane producing bacteria in methanogenic aggregates was theoretically evaluated by the calculation of steady-state sulfate microprofiles using a reference set of parameters obtained from the literature. The shooting method was used as a numerical technique for solving the mathematical model. The effect of the parameters on mass transport limitation was tested by varying each reference value of the parameters with a factor of 3. Sulfate limitation within granules prevailed at moderate (0.1 kg m-3) and low sulfate concentrations in the bulk liquid, at high maximum sulfate utilization rates (3.73 × 10-5 kg SO42- kg-1 VSS S-1 or biomass concentrations (40 KG VSS m-3), and in large aggregates (radius of 7.5 10-4 m). The effective diffusion coefficient of sulfate and the affinity constant were less determinative for the penetration depth of sulfate within a granule. © 1994 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 44 (1994), S. 642-648 
    ISSN: 0006-3592
    Keywords: waste gas treatment ; ethene ; volatile organic compounds ; granular activated carbon ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A packed granular activated carbon (GAC) biobed, inoculated with the ethane-degrading strain Mycobacterium E3, was used to study ethene removal from a synthetic waste gas. Ethene, for which the dimensionless partition coefficient for an air-water system at 20°C is about 7.6, was used as a model compound for poorly water soluble gaseous pollutants. In a first mode or operation, the GAC biobed was sprinkled intermittently and the waste gas influent was continuously pre-humidified, establishing relatively moist conditions (water content 〉40% to 45%). A volumetric ethene removal rate of 0.382 kg COD · m-3 · d-1 (0.112 kg ethene · m-3 · d-1) was obtained for an influent concentration of 125 ppm, a superficial waste gas velocity of 3.6E-3 m · s-1 and a pseudo residence time of 45 s. However, in the second mode of operation, omitting the pre-humidification of the waste gas influent and establishing a “dry” biobed (water content 〈40% to 45%), and thus obtaining better mass transfer to the biofilm, the ethene removal could be doubled for otherwise comparable operating parameters. Furthermore, under decreased wetting and for the given experimental conditions (influent concentration 125 to 816 ppm, waste gas superficial velocity 3.0E-3 m ·s-1, pseudo waste gas residence time 43 s), the ethene removal was not limited by mass transfer of ethene through the water layer covering the biofilm. © 1994 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Journal of Chemical Technology AND Biotechnology 59 (1994), S. 321-333 
    ISSN: 0268-2575
    Keywords: wastewater treatment ; biosensor ; on-line monitoring and control ; mass transfer ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: A respirographic biosensor is presented that is capable of monitoring the waste load and potential toxicity of wastewaters, both off-line in a laboratory or on-line at the wastewater treatment plant. The principles of the sensors' operation have been developed and implications of the design choices evaluated. Short term BOD values were obtained every 30 min. The linear dynamic range spanned concentrations differing by a factor of 5000. This range could be expanded by a factor of 10 by adjusting the aeration rate of the bioreactor in the sensor. The response time for toxicity detection was approximately 1 h. The use in the sensor of activated sludge from the plant concerned ensured relevant toxicity information was obtained. To check the condition of the sludge, an independent respiration measurement is proposed. When a siginificant activity change is observed, the sludge in the sensor must be replaced. The presence of oxidoreduction chemicals can cause interferences that may lead to measurement errors. Based on a difference in reaction kinetics, their presence can be assessed and the effect eliminated. Both on-line and laboratory applications in the chemical industry are presented. Special emphasis is given to the usefulness of the sensor data for waste management of production divisions. On-line assessment of load variations and hydrogen peroxide spills are given as illustrations of the implementation of the sensor on the treatment plant. Attention is drawn to the potential application of the data for process control and improved performance of the treatment plant.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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