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  • 1990-1994  (3)
  • Occupational Health and Environmental Toxicology  (2)
  • Inorganic Chemistry
  • 1
    Electronic Resource
    Electronic Resource
    Electromagnetic pulsed-wave radiation in spherical models of dispersive biological substances (1991)
    New York, NY [u.a.] : Wiley-Blackwell
    Bioelectromagnetics 12 (1991), S. 319-333 
    Details
    ISSN: 0197-8462
    Keywords: pulse-train ; dispersive dielectrics ; Fourier transform ; focusing ; hot-spot ; Life and Medical Sciences ; Occupational Health and Environmental Toxicology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Physics
    Notes: In analytical studies, we investigated induced-field patterns and SAR distributions in a lossy, dispersive, homogeneous, dielectric sphere typical of muscle tissue as irradiated by a plane-wave pulse train consisting of a pulse-modulated sinusoidal carrier wave. Calculations were made for carrier frequencies of 1, 3, and 15 GHz, pulse widths of 0.333, 2.0 and 4 ns, and pulse repetition rates of 1.11 × 106, 100 × 106, and 181.18 × 106 pps. The classical Mie solution was modified for a train of incident pulses that was represented by a Fourier series, and the fast-Fourier transform was used to sum the series. Computationally, the technique proved to be feasible and less expensive than we expected. The calculated field patterns show that the sphere's physical dimensions and the internal wavelength of the carrier greatly influence the nature of pulse-train propagation in the sphere. Harmonics having internal wavelengths nearly equal to the radius of the sphere produce most of the absorption; other harmonics produce little absorption. An intense hot spot is observed in spheres with radii that match the carriers' wavelengths.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bem.2250120602
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  • 2
    Electronic Resource
    Electronic Resource
    Determination of the Enthalpies of Formation of DyI2 and DyI3 and estimation of the Dy3+/Dy2+ standard aqueous electrode potentialDedicated to Professor Rudolf Hoppe on his 70th Birthday (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 616 (1992), S. 162-168 
    Details
    ISSN: 0044-2313
    Keywords: Dysprosiumdiiodide ; dysprosium triiodide ; enthalpy ; electrode potential ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Bestimmung der Bildungsenthalpien von DyI2 und DyI3 sowie Abschätzung des Dy3+/Dy2+-Standardelektrodenpotentials in wäßrigem MediumDyI2 and DyI3 wurden nach Literaturmethoden hergestellt. Ihre Lösungsenthalpien wurden bestimmt und die Bildungsenthalpien zu ΔfH°(DyI3, s, 298 K) = -(394 ± 16) kJ · mol-1 und ΔfH°(DyI2, s, 298 K) = -(616 ± 10) kJ· mol-1 berechnet. Entsprechenden Literaturangaben sowie geschätzten Lösungsenthalpien und Standardentropien wurde E°(Dy3+/Dy2+, aq.) zu -(2.6 ± 0.2) V berechnet. Ein Vergleich der Enthalpien für die Reduktion von DyI3 zu DyI2 bzw. DyI zu DyI2 wird vorgenommen.
    Notes: DyI2 and Dy3I were synthesized by literature techniques. Their enthalpies of solution were determined and their enthalpies of formation calculated to be ΔfH°(DyI2, s, 298 K) = -(394 ± 16) kJ· mol-1 and ΔfH°(DyI3, s, 298 K) = -(616 ± 10) kJ· mol-1. With appropriate literature and estimated enthalpies of solution and standard entropies, the E°(Dy3+/Dy2+, aq) was calculated to be -(2.6 ± 0.2) V. A comparison is made of the enthalpies of reduction of DyI3 to DyI2 and of DyCl3 to DyCl2.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926161025
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  • 3
    Electronic Resource
    Electronic Resource
    Temporal bisection in rats: The effects of high-peak-power pulsed microwave irradiation (1993)
    New York, NY [u.a.] : Wiley-Blackwell
    Bioelectromagnetics 14 (1993), S. 459-478 
    Details
    ISSN: 0197-8462
    Keywords: high-peak-power pulsed microwaves ; time perception ; time discrimination ; decision-making ; rats ; Life and Medical Sciences ; Occupational Health and Environmental Toxicology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Physics
    Notes: The effects of high-peak-power, pulsed microwaves on a time perception and discrimination task were studied in rats. Exposures were performed with the TEMPO exposure system, which produces an 80 nanosecond pulse with peak-power levels in excess of 700 megawatts. The ability to expose animals to such fields within a controlled environment is unique. As determined by calorimetry, a maximal, whole-body-averaged, specificabsorption rate of 0.072 W/kg was produced. Thus exposures were well below a recommended SAR limit of 0.4 W/kg. Power levels of transmitted microwaves were varied over a 50 dB range to obtain ascending and descending dose-response functions for each of the behavioral measures. Measures of time perception, response bias, and total trials did not change with power level. Dose-response effects were observed for discriminability (ability to distinguish between durations), session time, and trial completions (null responses, failures to respond on a trial). Covarying sound and X-ray exposures produced by TEMPO did not reliably correlate with the observed microwave effects. The observation of repeatable dose-response effects on discriminability and null responses indicates that the microwave exposures were affecting cognitive function in the rats, particularly the decision-making process. © 1993 wiley-Liss, Inc.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bem.2250140507
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    Paper (German National Licenses)
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