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Digitale Medien

Amalgam electrodes: Direct electrochemical generation of cadmium macrocyclic complexes (1992)

Boudon, C. ; Gisselbrecht, J. P. ; Gross, M.

Weinheim : Wiley-Blackwell

Electroanalysis 4 (1992), S. 19-26

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Details

ISSN: 1040-0397

Schlagwort(e): Amalgam electrode ; cadmium ; macrocyclic complexes ; Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The electrochemical oxidation of cadmium amalgam was studied in the nonaqueous solvents CH2Cl2, 1,2-C2H4Cl2 and propylene carbonate. Significant coordination effects were observed between the electrogenerated Cd(II) ions and 18-membered macromonocyclic ligands, each containing six Lewis bases heteroatoms: 18-O6, 18-S6, 18-N2O4, and 18-N6. The stoichiometries and the stabilities of the resulting complexes were determined. These stabilities increase from 18-O6 or 18-S6 to 18-N6.

Zusätzliches Material: 3 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/elan.1140040106

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