ISSN:
0009-2940
Keywords:
Phthalocyanines
;
dienophilic and enophilic
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Synthesis of Dienophilic and Enophilic PhthalocyaninesFrom 1,2,3,4-tetrahydro-2,3-dimethylen-1,4-epoxynaphthalene-6,7-dicarbonitrile (2) or the corresponding 1,3-diimino-1,3-dihydroisoindole 3 the hexadecahydro-octamethylenetetraepoxynaphthalocyanine 4 as well as the nickel and the iron complexes 5 and 6 containing enophilic side groups have been synthesized. From 1,4-dihydro-1,4-epoxynaphthalene-6,7-dicarbonitrile (8) and its corresponding 1,3-diimino-1,3-dihydroisonindole 9 the octahydro-tetraepoxynaphthalocyanines 10, 11, and 12, respectively, which contain dienophilic substituents, are obtained. 11 reacts with 2,3-dimethylbutadiene to form the adduct 13.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270119
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