ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Absolute rate constants for the one electron oxidation of guanine, guanosine, uric acid, xanthine, hypoxanthine, tyrosine, and thymine by various halogenated peroxyl radicals in aqueous solutions have been determined using the technique of pulse radiolysis. Roughly, linear correlations have been observed between the logarithm of these rate constants and Taft's inductive parameter (σ*) for the radicals. However, the rate constants for the radical CBr3O2· are slightly higher than those for CCl3O2· for most of these compounds. © John Wiley & Sons, Inc.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550241202
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