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  • 1990-1994  (4)
  • Polymer and Materials Science  (4)
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Year
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 41 (1990), S. 2273-2283 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Copper sulfide-polymer composite was prepared by depositing copper into porous polyolefine film with a method of electroless plating and sulfurizing the copper. The composite was an n-type semiconductor and useful as a component of p-n junction device and as a gas detector. The method was also useful for the preparation of silver sulfide-, nickel sulfide-, and cobalt sulfide-polymer composites.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Charged copolymers, polyacrylonitrile, having grafts of quaternized poly(N,N-dimethylaminoethylmethacrylate) and poly(sodium p-styrenesulfonate), were synthesized by photograft-polymerization. The charged ultrafiltration membranes, which had heterogeneous porous structures, were prepared by casting graft polymer solution containing poly(vinyl alcohol) into water.The permeation of nonionic dextran and anionic dextransulfate through the charged membranes was studied by ultrafiltration in aqueous solution. The molecular weight cutoff characteristics of the charged membrances were obtained using dextrans of various molecular sizes. The permeation behavior was discussed in terms of the charge effect of the graft polymers and electrostatic interaction between the polymers and the solute molecules.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 2183-2188 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Urease and glucose oxidase were immobilized by positively charged nylon gel matrix made from dimethylaminated nylon. The stability of the immobilized enzyme after preheating and incubation in organic solvent were measured and compared with that of native enzymes. Also, pH dependency of the immobilized enzymes was examined. The pH activity curves of the immobilized enzyme shift toward a low pH compared with that of the native enzyme. Using the pH difference, the electrostatic potential of the positively charged nylon gel was estimated. The estimated values of the positively charged gel were +90 and +102 mV for the immobilized urease and immobilized glucose oxidase, respectively. In the presence of buffer salt, they decreased to +30 and +24 mV, respectively. © 1992 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 47 (1993), S. 1773-1779 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Ultrasmall CdS particles, whose average size was controlled by thiols to range from 2 to 4 nm, were embedded in poly(vinyl alcohol) films. Shift of the fluorescence peak associates with the shift of the absorption threshold of the films, and the fluorescence intensity increases with the decrease in the size of CdS. Laser ablation at 308 nm was investigated by monitoring the emission spectra. Third-harmonic generation was measured for various sizes of CdS particles, and the optical nonlinearity in the nonresonance region was found to remain almost constant in the diameter range studied. © 1993 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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