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X-ray crystal structure of di-μ-carbonyldicarbonyl-bis(η5-pentamethylcyclopentadienyl)diruthenium (1994)

Batsanov, A. S. ; Struchkov, Yu. T.

Springer

Russian chemical bulletin 43 (1994), S. 503-504

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ISSN: 1573-9171

Keywords: X-ray diffraction study ; ruthenium(II) η-complexes ; the metal-metal bond ; the inductive effect

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract An X-ray diffraction study of [(η5-C5Me5)Ru(CO)(μ-CO)]2 was performed, revealing its dimeric structure and centrosymmetrictrans conformation. The Ru-Ru bond length (2.758(1) Å) and the separation between the Ru atom and the plane of the η5-C5Me5 ligand (1.923 Å) are greater than those in the Cp analog and in the isostructural Cp and C5Me5 complexes of iron; this effect is due to the s inductive effect of the Me groups.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01169738

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