ISSN:
0268-2605
Keywords:
Dimethylantimony
;
trimethylantimony
;
analysis
;
hydride generation
;
aquatic speciation
;
GCAA
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reports in the literature that the compounds MeSb(O)(OH)2 and Me2Sb(O)(OH) are present in marine and fresh-waters need to be re-examined. The results of several synthetic strategies suggest that these methylantimony(V) compounds are either environmentally inaccessible or polymeric in nature. Pure samples of various di- and tri- methylated antimony(V) species were prepared and found to undergo molecular rearrangement reactions when subjected to hydride generation procedures typically used for aquatic speciation.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aoc.590060215
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