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  • 1
    Electronic Resource
    Electronic Resource
    Antimon(III)-butoxo-Verbindungen (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 609 (1992), S. 35-38 
    Details
    ISSN: 0044-2313
    Keywords: Antimony(III)-butoxo compounds ; syntheses ; vibrational spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Antimony(III)-butoxo CompoundsTri(tert.-butoxo)stiban 1 reacts with antimony(III) chloride dependent from the molar ratio to yield Sb(OtBu)2Cl 2 and Sb4Cl7O(OtBu)3 3 resp ‥ 3 are discrete molecules with a cage structure. 2 is associated by oxygen bridges. The vibrational spectra of 1-3 are assigned.
    Notes: Tri(tert.-butoxo)stiban 1 reagiert mit Antimon(III)-chlorid in Abhängigkeit von der Stöchiometrie unter Bildung von Sb(OtBu)2Cl 2 bzw. Sb4Cl7O(OtBu)3 3. 3 besteht aus diskreten Molekülen mit Käfigstruktur. 2. ist über O-Brückenbindungen hochassoziiert. Die Schwingungsspektren von 1-3 werden zugeordnet.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926090306
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  • 2
    Electronic Resource
    Electronic Resource
    Dimethyldithiocarbamatostibane (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 617 (1992), S. 72-78 
    Details
    ISSN: 0044-2313
    Keywords: Ionic antimony(III)-dithiocarbamates ; syntheses ; structure ; vibrational and mass spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: DimethylaminodithiocarbamatostibanesThe Halogeno-bis(dimethylaminodithiocarbamato)stibanes (dtc)2SbCl 2 and (dtc)2SbBr 3 are prepared from (dtc)3Sb 1. Reaction of 2 and 3 resp. with CF3SO3SiMe3 yields the ionic compounds (dtc)2Sb+CF3SO3-4 and (dtc)2Sb+]2Br-(CF3SO3-) CH2Cl2 5 by elimination of Me3SiHal. The molecular structure of 4 is determined by X-ray analysis. The vibrational and mass spectra of 1-5 are reported and briefly discussed.
    Notes: Die Synthese der Halogeno-bis(dismethylaminodithiocarbamato)stibane (dtc)2SbCl 2 und (dtc)2SbBr 3 aus (dtc)1 wird beschrieben. Umsetzungen von 2 bzw. 3 mit CF3SO3SiMe3 führen unter Me3SiHal-Abspaltung zu den salzartigen Verbindungen (dtc)2Sb+CF3SO- 3 4 bzw. [(dtc)2Sb+]2Br-(CF3SO3-). CH2Cl2 5. 4 wird röntgenstrukturanalytisch charakterisiert. Die Schwingungs- und Massenspektren von 1-5 werden diskutiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926170111
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    Paper (German National Licenses)
    Fulltext
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