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  • 1
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The behaviour of epoxy acrylic coatings (on tin plated steel) when contacted with aqueous solutions of hydrochloric acid and a citrate buffer solution has been examined. The behaviour can be explained by assuming that the coatings contain defects which allow the solutions to penetrate them and contact the underlying metal.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 24 (1994), S. 1244-1248 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The effectiveness of sodium silicate (Na2SiO3) and trisodium phosphate (Na3PO4) as corrosion inhibitors for iron in 0.1 m NaClO4, in both aerated and deaerated solutions has been investigated. Both sodium silicate and trisodium phosphate are effective inhibitors in unbuffered solutions as a result of inhibiting the rate of the anodic iron dissolution reaction. However, the inhibition of the corrosion rate in the (final) pH range 9.6–11.6 is entirely due to the change in pH which the addition of Na2SiO3 and Na3PO4 to unbuffered solutions causes, and not to the presence of silicate/phosphate species. Where the final pH was in the range 5–7 addition of I mm sodium silicate to acidified aerated unbuffered solutions caused slight inhibition of the iron dissolution reaction when compared with a solution of the same pH. Lower concentrations of Na2SiO3 at the same final pH did not cause inhibition. Silicic acid has an approximate solubility of 1 mm and it is likely that the inhibitive behaviour in this pH range is due to the precipitation of H2SiO3 at the electrode surface. An aerated phosphate buffer of pH 7.0 inhibited both the anodic and cathodic reactions when compared with a 0.1 m sodium perchlorate solution at the same pH. This was due to the presence of phosphate species at the electrode surface. In carbonate and acetate buffers neither Na2SiO3 nor Na3PO4 caused corrosion inhibition.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-5036
    Keywords: amorphous aluminium phosphate ; amorphous iron phosphate ; neutron irradiation, phosphorus ; strengite ; variscite ; 32P
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The availability to plants of phosphorus (P) derived from sparingly soluble iron and aluminium phosphates was directly assessed with 32P labelled compounds in two glasshouse trials. In the first experiment, the comparative availability of all mineral phosphate (P) compounds to maize increased with time (14 to 42 days post emergence) and plant total P uptake, but P source did not affect the growth or total plant uptake of P. The comparative availability of the amorphous AlPO4 (Al-P), crystalline AlPO4 (variscite), amorphous FePO4 (Fe-P), and crystalline FePO4 (strengite) compared to KH2PO4 (=100) was 53.1, 3.4, 38.9, and 1.9%, respectively. In the second experiment, the availability of Fe-P, strengite, and KH2PO4 to several topical crop species was examined. There was no difference between maize, sorghum, mungbean, cowpea or soybean in their ability to utilise Fe-P or KH2PO4, although maize utilised strengite more than the other species. The major difference between these species in their ability to acquire P appears to be a difference in ability to locate soluble soil P rather than differences in their ability to access different pools of soil P. The advantages of using neutron irradiation to directly measure P absorption from mineral P compounds over traditional methodologies is discussed.
    Type of Medium: Electronic Resource
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