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  • 1990-1994  (2)
Material
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 23 (1993), S. 483-486 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract This paper reports a study of the influence of CO2 partial pressure and the cation of the supporting electrolyte on the electrochemical reduction of CO2 at copper electrodes in aqueous solution at 25°C. Both current efficiency (CE) and the rates of formation of the reduction products diminish linearly with decreasing CO2 pressure, while evolution of hydrogen increases. The product distribution was greatly influenced by the supporting electrolyte cation. The CE for the formation of C2H4 increased with cation in the order Cs+≈ K+ 〉 Na+ 〉 Li+, apparently in a manner related to the size of the cation radius. The non-metallic cation NH+ 4 allowed only hydrogen evolution with a CE of about 92%.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Geotechnical and geological engineering 9 (1991), S. 1-26 
    ISSN: 1573-1529
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Summary The Corinth Canal crosses the isthmus of Corinth and is of great importance for Mediterranean navigation as well as the railroad and highway connections between southern and central Greece. In the century-long history of the Canal, the slopes have shown only minor stability problems despite their significant length, very steep inclination and, more importantly, the strong earthquakes that have frequently shaken the Corinth area. This type of unsual behaviour has motivated research into the mechanical behaviour of the bluish grey marl which is the main geological formation in the Canal area. Geotechnical investigation of the Corinth Canal marl was performed with an extensive laboratory testing programme on high quality undisturbed samples of the intact marl. The material was shown to exhibit brittle behaviour, high stiffness and significant apparent cohesion at low and moderate stress levels. These characteristics indicate that the material possesses significant structural bonding which is believed to be due to cementation between individual particles, caused by the deposition of carbonates at the time of material genesis. With stressing, the material yields due to a gradual bond degradation. The locus of the initial yield points (yield surface) seems to be an ellipse oriented along the isotropic axis. The testing programme was supplemented with a series of tests on the de-structured marl obtained by thorough remoulding. These tests showed a significant difference in the pre-yield stiffness and the peak strength at low stress levels, but comparable post-rupture shear strengths.
    Type of Medium: Electronic Resource
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