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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Growth of a natural buffer layer has been observed for DyBa2Cu3O7−x films grown on Si substrates. The best DyBa2Cu3O7−x film, grown by molecular beam epitaxy with ozone as a source of activated oxygen, was 2300-A(ring) thick, highly c-axis oriented, and had a resistive-transition onset at 90 K and zero resistance by 70 K. The natural buffer layer, which grew at the interface of the DyBa2Cu3O7−x film and the Si substrate, consisted of Si, Ba, and O. Transmission electron microscopy on this film revealed a 150-A(ring) amorphous layer, whereas Auger electron spectroscopy depth profiling showed 400 A(ring) of chemical interdiffusion.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 2968-2972 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The stability of a cylindrical pore in an infinite medium, or of an infinite cylinder, when surface energy is significant is considered. The growth of small sinusoidal perturbations by viscous flow (creeping flow) or by evaporation/condensation are examined. The principal results are the dependence of perturbation growth rate on perturbation wavelength. For the creeping flow case no maximum in perturbation growth rate appears. The results are compared with those of Lord Rayleigh [Philos. Mag. 34-207, 145 (1892)] and of Nichols and Mullins [Trans. AIME 233, 1840 (1965)].
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 8502-8505 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Observation of magneto-optical transitions in a Si center δ-doped quantum well is reported. The excitons are stabilized by the application of the field. With photoluminescence excitation spectroscopy (PLE), transitions below the Fermi level are observed. At magnetic fields (approximately-greater-than)8 T broadened Landau levels can be seen. The features in the PLE spectra sharpen up significantly when the Larmor diameter becomes less than the average interimpurity spacing. The effect of the ionized donors in the well on the optical spectra is discussed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 572-577 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We provide a unified discussion of kinetic phase transitions for mean-field and lattice–gas treatments of the monomer–dimer surface reaction. For high surface mobilities, kinetics is typically well described by mean-field rate equations. These reveal bistability over a range of monomer adsorption rates which diminishes with increasing nonreactive monomer desorption rate d, and vanishes at some critical d=dc. Relative stability in the bistable region is determined from the behavior of chemical waves corresponding to the displacement of one stable state by the other. Their evolution is determined via appropriate reaction–diffusion equations. Conventional diffusion terms are modified here to reflect the influence of the presence of one species on diffusion of the other. We determine equistability (i.e., discontinuous transition) points for d≤dc, and thus construct a kinetic phase diagram including a spinodal line. For lower surface mobilities, analysis of lattice–gas models reveals qualitatively analogous behavior. The key difference is that for lower mobilities, spontaneous fluctuations are effective in automatically selecting the most stable state, i.e., in reducing metastability, and thus producing discontinuous transitions.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 9018-9025 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have investigated the diffusion of clusters on a triangular lattice using Monte Carlo simulations. A cluster is defined as a two-dimensional collection of particles which are connected to each other, either directly or indirectly through other particles in the cluster, by nearest-neighbor bonds. Each particle is allowed to hop, with probability αδb/2/(α−δb/2+αδb/2), to a vacant nearest-neighbor site with the constraint that the hop does not break the cluster. The change in the number of bonds is given by δb. The equilibrium clusters are correlated animals with structure controlled by the parameter α. We show that the diffusion coefficient of a cluster can be decomposed into two factors. One is a measure of the weighted length of the "active'' perimeter and the other is a measure of the correlation between pairs of steps taken by the cluster during its walk. The perimeter measure is asymptotically proportional to cluster size N, as anticipated for ramified animals, but it crosses over to N1/2 dependence for smaller compact clusters with α〉1. Our focus is on the accurate determination of the size and structure dependence of the correlation factor, which is more sensitive to statistical fluctuations. As a result, we describe the scaling of the cluster diffusion coefficient with cluster size.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 8397-8398 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Irreversible adsorption of diatomics on crystalline surfaces is sometimes modeled as random dimer filling of adjacent pairs of sites on a lattice. We note that this process can be implemented in two distinct ways: (i) randomly pick adjacent pairs of sites, jj', and fill jj' only if both are empty (horizontal transition state); or (ii) randomly pick a single site, j, and if j and at least one neighbor are empty, then fill j and a randomly chosen empty neighbor (vertical transition state). Here it is instructive to consider processes which also include competitive random monomer filling of single sites. We find that although saturation (partial) coverages differ little between the models for pure dimer filling, there is a significant difference for comparable monomer and dimer filling rates. We present exact results for saturation coverage behavior for a linear lattice, and estimates for a square lattice. Ramifications for simple models of CO oxidation on surfaces are indicated.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 96 (1992), S. 4805-4807 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Various features of NO+CO reaction kinetics on Pt(100) surfaces, including temporal oscillations, are well described by a three-variable model incorporating only the CO, NO, and O coverages. Here we analyze the corresponding reaction–diffusion equations demonstrating the existence of chemical waves where an "oscillating phase'' displaces an unreactive NO/CO phase leaving a spatially periodic structure in its wake; pulses excited via inhomogeneities from an unreactive NO/CO background; and Turing structures for sufficiently unequal NO and CO diffusion rates.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 1438-1439 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We consider the irreversible random sequential adsorption of particles taking k sites at a time, on a one-dimensional lattice. We present an exact expansion for the coverage, θ(t,k)=A0(t)+A1(t)k−1+A2(t)k−2+..., for times, 0≤t≤O(k), and at saturation t=∞. The former is new and the latter extends Mackenzie's results [J. Chem. Phys. 37, 723 (1962)]. For these expansions, we note that the coefficients Ai≥1(∞) are not obtained as large-t limits of the Ai≥1(t). Finally, we comment on the Laurent expansions for general O(k)〈t〈∞, which reveal the occurrence of additional kn terms, with n(approximately-greater-than)0.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: This paper describes the design and operation of a 40 spatial channel Thomson scattering system that uses multiple 20-Hz Nd:YAG lasers to measure the electron temperature and density profiles periodically throughout an entire plasma discharge. As many as eight lasers may be fired alternately for an average measurement frequency of 160 Hz, or they may be fired in rapid succession (〈10 kHz), producing a burst of pulses for measuring transient events. The high spatial resolution (1.3 cm) and wide dynamic range (10 eV–20 keV) enable this system to resolve large electron density and temperature gradients formed at the plasma edge and in the scrape-off layer during H-mode operation. These features provide a formidable tool for studying L–H transitions, edge localized modes (ELMs), beta limits, transport, and disruptions in an efficient manner suitable for large tokamak operation where shot-to-shot scans are impractical. The scattered light is dispersed by interference filter polychromators and detected by silicon avalanche photodiodes. Laser control and data acquisition are performed in real time by a VME-based microcomputer. Data analysis is performed by a MicroVAX 3400. Additional features of this system include real-time analysis capability, full statistical treatment of error bars based on the measured background light, and laser beam quality and alignment monitoring during plasma operation. Results of component testing, calibration, plasma operation, and error analysis are presented.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    Journal of Mathematical Physics 32 (1991), S. 2918-2922 
    ISSN: 1089-7658
    Source: AIP Digital Archive
    Topics: Mathematics , Physics
    Notes: Some exact results for a reversible version of the d=1+1 bridge site (or single-step) deposition model are presented. Exact steady-state properties are determined directly for finite systems with various mean slopes. These show explicitly how the asymptotic growth velocity and fluctuations are quenched as the slope approaches its maximum allowed value. Next, exact hierarchial equations for the dynamics are presented. For the special case of "equilibrium growth,'' these are analyzed exactly at the pair-correlation level directly for an infinite system. This provided further insight into asymptotic scaling behavior. Finally, the above hierarchy is compared with one generated from a discrete form of the Kardar–Parisi–Zhang equations. Some differences are described.
    Type of Medium: Electronic Resource
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