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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 2873-2876 
    ISSN: 0887-624X
    Keywords: polymeric sulfonium salts ; antibacterial activity ; polymeric disinfectant ; viable cell counting method ; cationic biocide ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 3003-3011 
    ISSN: 0887-624X
    Keywords: controlled-released biocides ; phosphonium biocides ; antibacterial activity ; self-sterilizing materials ; polyester ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyesters were prepared which retained phosphonium biocides as counter ions of sodium sulfonate moieties incorporated into the polymers, and surface antibacterial activity of the polyester films against Staphylococcus aureus and Escherichia coli was explored. These films exhibited a high surface antibacterial activity against S. aureus and E. coli, particularly against S. aureus, and the activity was affected by the structure and the compositional ratio of the phosphonium salts. Amount of the released phosphonium salts was very small, so that liberation of the phosphonium biocides can be expected to occur over a long period. Morphological changes of the cells of S. aureus and E. coli in contact with the polyester films were evaluated by scanning electron microscopy. It was found that the surface antibacterial activity of the polyester films was rather bacteriostatic than bactericidal as evidenced by no morphological changes of the bacterial cells in contact with the phosphonium biocides © 1993 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 335-343 
    ISSN: 0887-624X
    Keywords: polymeric phosphonium salts ; antibacterial activity ; viable cell counting method ; cationic disinfectant ; polymeric biocide ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Various polymeric phosphonium salts and the corresponding low-molecular-weight model compounds were prepared and their antibacterial activities against Staphylococcus aureus and Escherichia coli were explored by the viable cell counting method in sterile distilled water. Antibacterial activity of the polymers was found to be higher than that of the corresponding model compounds, particularly against S. aureus. Furthermore, the polymeric phosphonium salt exhibited a higher activity by 2 orders of magnitude than the polymeric quaternary ammonium salt with the same structure except the cationic part. Compounds with the longest alkyl chain (octyl) studied were found to exhibit particularly high activity, and this finding may be ascribed to the contribution of the increased hydrophobicity of the compounds to the cidal activity. © 1993 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 1441-1447 
    ISSN: 0887-624X
    Keywords: polymeric phosphonium salts ; antibacterial activity ; effect of counter anion ; effect of molecular weight ; viable cell counting method ; polymeric biocide ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Various poly[tributyl(4-vinylbenzyl)phosphonium salt]s with different counter anions were prepared and their antibacterial activities against Staphylococcus aureus were explored by the viable cell counting method in sterile distilled water. Antibacterial activity was found to be affected by the structure of the counter anions. The activity was low for a counter anion which tends to form a tight ion-pair with phosphonium ion, while it was high for those facilitating ionic dissociation to free ions. Furthermore, the molecular weight dependence of the antibacterial activity was investigated for poly[tributyl(4-vinylbenzyl) phosphonium chloride] with various molecular weights against S. aureus. Antibacterial activity was found to increase with molecular weight. Various copolymers were prepared in which the compositional ratio of tributyl(4-vinylbenzyl)phosphonium chloride to acrylamide, N-vinyl-2-pyrrolidone, or styrene was altered, and the effect of the positive charge density on the antibacterial activity was investigated against S. aureus. Antibacterial activity of the copolymers was much higher than that of the low-molecular-weight model compound and enhanced with the molar fraction of the phosphonium units in the copolymers. © 1993 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 1997-2001 
    ISSN: 0887-624X
    Keywords: polymers with pendant phosphonium salts ; antibacterial activity ; effect of side-chain length ; viable cell counting method ; polycationic biocides ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polymeric phosphonium salts with different side-chain length between the main chain and the active group, poly[4-2-tributyl-phosphonioethyl)styrene chloride-co-4-(2-chloroethyl)styrene] and poly[4-(3-tributylphosphoniopropyl)styrene chloride-co-4-(3-chloropropyl)styrene], were prepared and their antibacterial activities against Staphylococcus aureus and Escherichia coli were examined by the viable cell counting method in sterile distilled water. The antibacterial activity was found to decrease as the side-chain length increased. The most significant finding is a peculiar concentration dependence of the antibacterial activity, which demonstrated the presence of an optimal concentration. The observed specific effects of the side chain length and the concentration on the antibacterial activity seem to be ascribed to the state of aggregation of the polycationic biocides in aqueous solution. © 1994 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 1467-1472 
    ISSN: 0887-624X
    Keywords: polymeric phosphonium salts ; surface antibacterial activity ; immobilized biocides ; viable cell counting method ; surface photografting ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Immobilized polycationic biocides with phosphonium salt on the surface of poly(propylene) film were prepared by surface photografting and surface antibacterial activity of the resulting films against Staphylococcus aureus and Escherichia coli was explored by the viable cell counting method. These films with phosphonium salts were found to exhibit high antibacterial activity against S. aureus and E. coli - particularly against E. coli. Furthermore, morphological changes of the cells of S. aureus and E. coli in contact with the immobilized phosphonium salt were estimated by scanning electron microscopy. It was found that the immobilized biocides exhibited surface bactericidal activity against both strains as evidenced by shrunken and deformed cells of these species in contact with the immobilized biocides. © 1993 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 3031-3038 
    ISSN: 0887-624X
    Keywords: polymeric phosphonium salts ; main chain ; antibacterial activity ; viable cell counting method ; cationic biocides ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polymers with phosphonium salts and different alkyl spacers in the main chain were prepared, and their antibacterial activities against Staphylococcus aureus and Escherichia coli were explored by the viable cell counting method in sterile distilled water. The antibacterial activity of the polymers was found to be higher than that of the corresponding model compounds against each strain, and the effect of the molecular weight on the antibacterial activity was also observed for the compounds with the same spacer length. The antibacterial activity of the polymer samples bonded with different spacer lengths was found to increase with increasing the spacer length against both strains. © 1993 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Various polymeric phosphonium salts containing long alkyl chains (C10—C18) and their corresponding model compounds were prepared, which possess the same hydrophobic structure as that of the common disinfectants (quaternary ammonium salts), and their antibacterial activities were evaluated by means of the viable cell counting method against Staphylococcus aureus (Gram-positive) and Escherichia coli (Gram-negative). The polymer with the decyl group exhibited a higher activity than that of the corresponding model compound, particularly against the Gram-positive strain. Furthermore, antibacterial activity of the polymers was found to decrease as the chain length increased. In contrast with the polymers, the antibacterial activity of the corresponding model compounds increased as hydrophobicity of the substituents increased. The antibacterial activity was strongly dependent on the structure, particularly on the length of the alkyl chain. © 1994 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 54 (1994), S. 1305-1310 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Phosphonium salts with different alkyl chains as substituents were incorporated covalently on the surfaces of cellulose filters with silane coupling agents containing phosphonium ions, and their surface antibacterial activities against Staphylococcus aureus and Escherichia coli were explored by the viable cell-counting method in sterile distilled water. The filters incorporating phosphonium biocides showed higher antibacterial activity, and its activity strongly depended on the structure of substituents. The surface-treated filters may be used to sterilize air and water, including microorganisms. © 1994 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Alkoxysilane with phosphonium biocides as coupling agents were covalently attached to cotton-fiber surfaces, and the antibacterial activity of the surface-treated fibers against Staphylococcus aureus and Escherichia coli was evaluated by the viable cell counting method in sterile distilled water. These fibers with phosphonium salts were found to exhibit high antibacterial activity against S. aureus and E. coli, particularly against S. aureus, and the activity increased as hydrophobicity of the substituents bonded directly to phosphonium ions increased. Furthermore, morphological changes of the cells of S. aureus and E. Coli in contact with the fibers were evaluated by scanning electron microscopy. It was found that the fiber with the phosphonium biocides exhibited bacteriostatic as well as bactericidal activity against both strains, which was evident from observation of normal and deformed cells of these species in contact with the fibers. © 1994 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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