ISSN:
1572-8927
Keywords:
Excess dielectric permittivities and molar polarization
;
N-methylbenzenesulfonamide mixtures benzyl alcohol
;
1,4-dioxane
;
1,2-dichloroethane
;
hexamethylphosphortriamide
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The dielectric permittivities of binary mixtures of N-methylbenzenesul-fonamide (N-MBS) with benzyl alcohol, 1,2-dichloroethane, 1,4-dioxane and hexamethylphosphortriamide were measured as a function of mole fraction over the whole composition range at 30 and 50°C. The excess dielectric permittivities and the excess molar polarizations were also calculated. The excess dielectric permittivities εE and excess molar polarizations PE were found to be negative for N-methylbenzene-sulfonamide mixtures with benzyl alcohol and 1,4-dioxane, εE values were positive and PE values negative for mixtures with 1,2-dichloroethane, and εE and PE values were clearly positive for mixtures with hexamethylphosphortriamide. The results are discussed in terms of the strength of the dipolar and hydrogen-bonding interactions between the molecules in various binary mixtures.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00647019
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