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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 23 (1994), S. 569-577 
    ISSN: 1572-8927
    Keywords: Acetone ; crown ethers ; cryptands ; complex formation ; ion pairs ; alkali metal ions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Stability constants and thermodynamic values for the complex formation of alkali ions by crown ethers, diaza crown ethers and cryptands have been measured by means of potentiometric and calorimetric titrations in acetone as solvent. The interactions between the ligands and solvent molecules play an important role for the complex formation. Cryptands form the most stable complexes with alkali ions if inclusion complexes are formed. Even in the case that the salts are not completely dissociated in acetone the presence of ion pairs does not influence the calculated values of the stability constants.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of inclusion phenomena and macrocyclic chemistry 14 (1992), S. 91-99 
    ISSN: 1573-1111
    Keywords: Dye complexes ; inclusion compounds ; cyclodextrins ; cucurbituril
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The decomposition reactions of the dyes phenol blue and murexide were measured spectroscopically in acidic solution at different temperatures. From these reaction rates and their temperature dependence in the absence and presence of various hosts, the stability constants and the reaction enthalpies of the dye complexes with noncyclic dextrins, cyclodextrins and cucurbituril were calculated.β-Cyclodextrin enhances the stability of phenol blue in acidic solution. This effect is even more pronounced with cucurbituril. Due to the molecular structure of murexide this dye cannot form inclusion complexes with hosts containing hydrophobic cavities.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 65 (1993), S. 1131-1131 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Irradiation of biaxially stretched poly(ethyleneterephthalate) (PETP)-films by UV-excimer wavelengths gives rise to well-known morphological surface modifications. Using a slit or a circular aperture a characteristic pattern due to Fresnel diffraction is imprinted onto this effect. The diffraction of the laser light leads to local variations of intensity on the PETP-surface. Using this diffraction effect a hitherto unknown fluence threshold for the appearance of laser induced surface morphology can be determined. This threshold is markedly lower than the threshold for ablation obtained by conventional extrapolation of laser etching data. Using elastomeric fibers furthermore it is shown that the energy limit for the onset surface structures is dependent on the amount of externally applied tension fields.
    Notes: Bei UV-Excimer-Laserbestrahlung von biaxial verstreckten Poly(ethylenterephthalat) (PETP)-Folien durch einen Spalt oder durch kreisförmige Blenden entstehen unter geeigneten Bestrahlungsbedingungen die bekannten charakteristischen Strukturierungen, welche durch Fresnelsche Beugungserscheinungen modifiziert sind. Die Beugung des Laserlichtes führt zu lokalen Intensitätsunterschieden auf der PETP-Oberfläche. Unter Ausnutzung dieses Beugungseffektes wurde eine higher nicht gemessene Grenzenergie für die laserinduzierte Ausbildung der Oberflächenmorphologie von PETP bestimmt. Wesentlich ist hierbei, daß diese Strukturschwellenenergie deutlich unterhalb der extrapolierten Ablationsschwellenenergie von PETP liegt. Darüber hinaus wird an Elastomerfasern aufgezeigt, daß die Grenzenergie zur Strukturbildung auch von der Größe eines extern aufgebrachten Spannungsfeldes abhängt.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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