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  • 1990-1994  (2)
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  • 1
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 71 (1992), S. 3419-3426 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The preferred orientation of YBa2Cu3O7 thin films grown on single-crystal MgO(100) and SrTiO3(100) substrates has been investigated using x-ray diffraction and transmission electron microscopy. Various types of microstructural defects were identified in the films and correlated with a lowering of the critical current density Jc. On MgO substrates it was found that a film with 5% of its grains rotated 45° with respect to the dominant orientation and a high density of small-angle grain boundaries had Jc reduced by 75% compared to a film with no 45° grain boundaries and a low density of small-angle grain boundaries. On SrTiO3 substrates it was found that an increase in the amount of a-axis oriented material from 0.6% to 8.3% lead to a reduction in Jc by 70% . In general, higher critical current densities were found on SrTiO3 than on MgO substrates. This fact is attributed to the closer lattice match of YBa2Cu3O7 with SrTiO3, resulting in an in-plane mosaic spread of only 0.38° for the best film on SrTiO3 compared to 0.86° for the best film on MgO.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 3636-3646 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The effective heat of formation (ΔH') concept allows heats of formation to be calculated as a function of concentration. In this work the effective heat of formation rule is used to predict first phase formation in metal-aluminum thin-film systems and to predict subsequent phase sequence for thin metal films on thick aluminum or thin aluminum on thick metal substrates. The effective concentration at the growth interface is taken to be that of the lowest temperature eutectic (liquidus) for the binary system. Although the effective heat of formation rule may predict that formation of a certain phase would lead to the largest free energy change, this phase does not necessarily form at the moving reaction interface if it has difficulty to nucleate. By excluding phases with a large number of atoms per unit cell and which thus have difficulty to nucleate, the effective heat of formation rule successfully predicts first phase aluminide formation for all 15 metal-aluminum binary systems for which experimental data could be found. It is also shown how the effective heat of formation rule can be used to predict formation and decomposition of aluminide phases in contact with each other or in contact with their component metals.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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