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  • 1
    Electronic Resource
    Electronic Resource
    Photochemistry on rough metal surfaces (1984)
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 88 (1984), S. 4200-4209 
    Details
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/j150663a003
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    A new technique for the determination of surface adsorbate geometries utilizing second harmonic generation and absorption band shifts (1989)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 2683-2688 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A combination of second harmonic generation (SHG) and a simple dipole–dipole interaction model is presented as a new technique for determining adsorbate geometries on surfaces. The polarization dependence of SHG is used to define possible geometries of the adsorbate about the surface normal. General formulas for absorption band shifts using the geometry constraints imposed by the SHG data are derived for a dimer constructed from two arbitrarily placed monomers on the surface using the dipole–dipole interaction potential. These formulas can be used to determine the orientation of the two monomers relative to each other. A simplified version of this formalism is used to interpret absorption band shifts for a system of rhodamine B adsorbed on quartz.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.456978
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  • 3
    Electronic Resource
    Electronic Resource
    Studies of chemical reactivity in the condensed phase. IV. Density dependent molecular dynamics simulations of vibrational relaxation in simple liquids (1988)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 6687-6696 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Molecular dynamics simulations of the photodissociation/recombination process for iodine in liquid xenon at several densities are reported in this paper. These simulations were performed to aid in the understanding and interpretation of recent picosecond experimental investigations on model chemical reaction systems. From these calculations, it was found that geminate recombination occurs primarily within a few picoseconds at all densities considered. This is in agreement with previous molecular dynamics simulations with significantly smaller systems, and with the current interpretation of experimental results. Simulated iodine ground electronic state vibrational relaxation times range from about 1 ns at the lowest density to approximately 250 ps at the highest density reported here. In addition, the functional form of the decay of the average iodine vibrational energy was observed to be nearly independent of density. This result is discussed in terms of simple gas phase isolated binary collision models. Various force correlation functions projected onto the iodine vibrational coordinate were also examined, and indicate that the iodine molecule significantly perturbs the local solvent environment. These force correlation functions may be helpful when assessing the usefulness of liquid phase theories of vibrational relaxation of highly excited molecules. Finally, the simulation results on iodine vibrational relaxation are compared with the available experimental data. These comparisons indicate that the molecular dynamics calculations overestimate the rate of vibrational relaxation over the lower third of the iodine ground electronic state potential surface, and that the efficiency of V–TR transfer, relative to V–V transfer, may have been underestimated. The sensitivity of these results to several system parameters are analyzed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.455341
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  • 4
    Electronic Resource
    Electronic Resource
    The drying rates of component parts of inflorescence-bearing tillers of Italian ryegrass (1984)
    Oxford, UK : Blackwell Publishing Ltd
    Grass and forage science 39 (1984), S. 0 
    Details
    ISSN: 1365-2494
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Inflorescence-bearing tillers of Italian ryegrass (Lolium multiflorum cv. RvP) were dried in controlled temperature, relative humidity and air speed conditions chosen to be within the range likely to occur in a hay swath drying in the field. After drying for increasing intervals the tillers were separated into inflorescence, exposed flowering stem, leaf-laminae, leaf-sheath and flowering stem enclosed by leaf-sheath and the drying rates of these components in addition to that of whole tillers were measured. There were large differences in drying rate between components, but the differences were similar over the range of drying conditions employed. The drying rate of the inflorescence as well as that of stem enclosed by leaf-sheath was found to be very low and that of leaf-laminae and leaf-sheath very high.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1365-2494.1984.tb01692.x
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  • 5
    Electronic Resource
    Electronic Resource
    The influence of the epidermis on the drying rates of red clover leaf petioles and stems and of Italian ryegrass stems at low water contents (1984)
    Oxford, UK : Blackwell Publishing Ltd
    Grass and forage science 39 (1984), S. 0 
    Details
    ISSN: 1365-2494
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Previous results with red clover (Trifolium pratense) leaflets, leaf petioles and stems indicated that the epidermis continued to impose a barrier to water loss at low water contents. Further experiments with red clover leaf petioles and stems suggest that cuticular wax is the epidermal component concerned and that treatments which remove or merely modify this will also increase drying rate. However, when treatments to reduce epidermal resistance were applied to pseudostems and flowering stems of Italian ryegrass (Lolium multiflorum) the initial increase in drying rate produced was not sustained at low water contents. The pseudostems consisted of three layers of leaf material rolled one within the other and the true flowering stems were surrounded by one leaf sheath. Their pattern of response to treatments suggested that these affected only the outer sheath, which produced an initial acceleration in drying rate, but that this was not sustained after the outer sheath was dry because the lower untreated layers dried in a similar way to untreated controls.The results suggest the possibility of devising practical treatments to increase drying rate at low water contents with crops containing a high proportion of leaf or stem not surrounded by leaf sheath. Devising such treatments for crops with a high proportion of grass pseudostem or flowering stem surrounded by leaf sheath will be considerably more difficult.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1365-2494.1984.tb01666.x
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  • 6
    Electronic Resource
    Electronic Resource
    The influence of the epidermis on the drying rate of red clover leaflets, leaf petioles and stems at low water contents (1982)
    Oxford, UK : Blackwell Publishing Ltd
    Grass and forage science 37 (1982), S. 0 
    Details
    ISSN: 1365-2494
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: An apparatus is described which enables excised pieces of plant material lo be weighed al frequent intervals as they dry in controlled conditions of temperature, humidity and air-speed. The effect of removing the epidermis on the drying rate of red clover (Trifolium pratense) leaflets, leaf petioles and stems is examined. Initially this treatment caused a very large increase in the drying rate of leaflets. Although the effect declined as water content fell, leaflets from which the epidermis had been removed still dried more rapidly than the controls at a water content equivalent to 50% of the dry weight. Removing the epidermis had a greater effect on the drying rate of leaf petioles and stems at low water contents than it did on the drying rate of leaflets.Slow drying at low water contents is a major factor responsible for the undesirably long periods for which hay may lie in the field. Slow drying occurs even though swath microclimate becomes more favourable for drying as water content falls. The results presented here suggest that treatments which reduce cuticular resistance have the potential to reduce field drying time.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1365-2494.1982.tb01591.x
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  • 7
    Electronic Resource
    Electronic Resource
    Pathways of water loss from legumes and grasses cut for conservation (1980)
    Oxford, UK : Blackwell Publishing Ltd
    Grass and forage science 35 (1980), S. 0 
    Details
    ISSN: 1365-2494
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1365-2494.1980.tb01487.x
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  • 8
    Electronic Resource
    Electronic Resource
    The ‘Mini O2’ and ‘Healthdyne’ oxygen concentrators (1985)
    Oxford, UK : Blackwell Publishing Ltd
    Anaesthesia 40 (1985), S. 0 
    Details
    ISSN: 1365-2044
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: Two oxygen concentrators designed for home use, the ‘Healthdyne’ and the ‘Mini O2’, have been assessed with particular reference to their possible role in anaesthesia. Both were found to be a reliable source of oxygen enriched gas. Neither was fully capable of driving a gas powered ventilator satisfactorily, but both could potentially be very useful in normal and field anaesthetic practice.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1365-2044.1985.tb10661.x
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  • 9
    Electronic Resource
    Electronic Resource
    Effects of thiopentone, etomidate and propofol on the haemodynamic response to tracheal intubation (1988)
    Oxford, UK : Blackwell Publishing Ltd
    Anaesthesia 43 (1988), S. 0 
    Details
    ISSN: 1365-2044
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: The haemodynamic response to tracheal intubation was compared in 303 patients in whom anaesthesia was induced with either thiopentone 4 mg/kg, etomidate 0.3 mg/kg or propofol 2.5 mg/kg, with and without fentanyl 2 μg/kg. There was after propofol alone a significant decrease in arterial blood pressure, which did not increase above control values after intubation. Significant increases in arterial pressure followed intubation in patients induced with thiopentone or etomidate alone. Increases in heart rate occurred with all agents after laryngoscopy. The use of fentanyl resulted in arterial pressures lower than those after the induction agent alone, and in an attentuation, but not abolition of the responses to largyngoscopy and intubation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1365-2044.1988.tb09065.x
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  • 10
    Electronic Resource
    Electronic Resource
    Complex formation of polyethylenimine with sodium triflate and conductivity behavior of the complexes (1986)
    s.l. : American Chemical Society
    Macromolecules 19 (1986), S. 987-989 
    Details
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ma00158a009
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