Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
83 (1985), S. 3859-3862
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The diamagnetic MoF6 molecule intercalates into graphite (HOPG) according to the reaction nC+MoF6 → C+xn(MoF−6)x (MoF6)1−x. Combination of ESR and magnetic susceptibility measurements indicate that the charge transfer is incomplete with x∼0.2. The system HOPG/MoF6 is unique in that ESR resonances due to both the 4d1 intercalant species (MoF−6) and conduction carriers can be detected. The ESR spectra of stage III exhibit an additional resonance which is probably associated with graphite interior layers.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.449096
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