Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
82 (1985), S. 1907-1919
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Collisional energy transfer at 300 K of vibrationally highly excited CS2 molecules (excitation energies 28 660 and 32 640 cm−1) is studied directly by time resolved UV absorption spectroscopy after laser excitation at 351 and 308 nm. Average energies 〈ΔE〉 transferred per collision for 27 bath gases are derived. A marked dependence of 〈ΔE〉 on the excitation energy is noted; the steepness of this dependence is not the same for all bath gases. The results are compared with energy transfer data for vibrationally highly excited large molecules.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.448375
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