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  • 1985-1989  (5)
  • 1955-1959
  • 1940-1944
  • Chemical Engineering  (3)
  • 13C NMR  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Energy storage through magnesia sulfatation in a fluidized-bed reactor (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 519-523 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690340323
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Transport processes in narrow (capillary) channels (1985)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 473-482 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rates of mass and momentum transport in narrow flow channels (gaps 0.2-0.5 mm) have been determined over a wide range of flow velocities, 220-7,700 cm/sec (Re 1,300 to 22,000). Existing correlations that apply to smooth channels of much larger hydraulic diameter were found to be valid for the narrow channels as well. However, in the turbulent regime the condition of hydraulic smoothness could be satisfied only when the walls were optically smooth. Transport rates to rough walls were also measured. The ratio of the mass transport to the momentum transport in the form of jD/(f/2) - a measure of the improved mass transfer compared to the increased pressure drop - is given for the smooth and rough-wall cells over the Re range studied.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690310315
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    The effects of cure temperature on the thermomechanical properties of UV curable coatings (1989)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 1165-1168 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A method is presented to study the mechanical behavior of soft, UV curable coating material as a function of temperature of the prepolymer at cure. For such materials, the crosslink density (hence, equilibrium modulus) is found to decrease with increasing cure temperature. The three primary coatings are: a polyurethane acrylate with a nominal equilibrium tensile modulus of 200 psi, a polyurethane acrylate with a nominal equilibrium modulus of 1200 psi, and a non-urethane acrylate with a nominal equilibrium tensile modulus of 60 psi.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760291704
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    13C and proton nuclear magnetic resonance spectra of trans-[arylbromobis(triethyl phosphine)palladium(II)] and related compounds. The π-donor ability of the Ni(PEt3)2X, Pd(PEt3)2X and Pt(PEt3)2X groups (1986)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 24 (1986), S. 243-246 
    Details
    ISSN: 0749-1581
    Keywords: 13C NMR ; 1H NMR ; Ni-Pd-Pt series ; Ni-Pd-Pt substituent effects ; Ni/Pd/Pt-induced paramagnetic shifts ; M(PEt3)2X substituents ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 13C and proton NMR spectra of several arylpalladium and some arylnickel and arylplatinum complexes have been compared. The Ni(PEt3)2X and Pd(PEt3)2X substituents induce a paramagnetic shift of Cipso (of the phenyl ring) which is much larger than that induced by Pt(PEt3)2X. However, there are no significant differences along the Ni/Pd/Pt series for the ortho, meta and para positions. For the six compounds of general formula trans-[ArPdBr(PEt3)2] reported here, the mean Δ(δ)C values induced on the ArH by the introduction of the PdBr(PEt3)2 substituent are found to be 26.9 (Cipso), 7.2 (Cortho), -1.1 (Cmeta), -5.5 (Cpara), -0.03 (Hortho), -0.28 (Hmeta) and -0.38 ppm (Hpara).
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1260240311
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  • 5
    Electronic Resource
    Electronic Resource
    Investigation of prototropic equilibria by carbon-13 relaxation time analysis (1987)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 25 (1987), S. 16-20 
    Details
    ISSN: 0749-1581
    Keywords: 13C NMR ; 13C Relaxation Times ; Prototropic equilibria ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Quaternary 13C dipole-dipole spin-lattice relaxation times are used to analyse prototropic equilibria of 2-acetylbenzimidazole (1) and 4-azabenzimidazole in DMSO-d6 solutions. For the first compound, fast exchange between the two chelated structures prevails for 13C relaxation times, whereas proton and 13C chemical shifts characterize a slow exchange. For 4-azabenzimidazole, 13C and 1H spectra do not exhibit absorptions from structures in slow exchange. Analysis of the T1 values of carbons 8 and 9 before and after isotopic exchange of the labile amino hydrogen clearly show that the major component of the equilibrium is the 3H structure.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1260250105
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    Paper (German National Licenses)
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