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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 470-482 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A computer modeling concept was developed to deal with multicomponent emulsion copolymerization systems. Based on the model, a simulating program called NSBEC (n-component, semibatch emulsion copolymerization) was prepared., NSBEC is capable of carrying out a variety of operations involving any number of monomers with different modes of ingredient feed. In this paper, first the basic concept of the model is explained, then several applications to the actual experimental systems (e.g., acrylonitrile-vinylidene chloride, vinyl acetate-butyl acrylate, and methyl methacrylate-butyl acrylate) are discussed. Finally, the probable control of copolymer composition by means of the semibatch operation based on NSBEC is proposed. The authors expect that use of NSBEC can substantially reduce the number of experimental runs previously required to describe the system.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 10 (1985), S. 149-158 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An experimental study of semi-continuous emulsion copolymerization of acrylonitrile (AN) and styrene (ST) was carried cut with an isothermal stirred vessel. Continuous addition of monomer emulsion (ME) was inserted between preliminary and finishing batch operations. A mathematical model to simulate the experimental results was also developed with a particular attention on the partition of hydrophilic AN between the aqueous and organic phases. The result of simulation was quite satisfactory even though the approximate rate expressions proposed by Szabo and Nauman (1) were employed.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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