ISSN:
0032-3888
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Dynamic dielectric analysis (DDA) has been used to study curing polymer systems and thermoplastics. Measurements have been made over a frequency range of six decades. This wide range of frequencies increases the amount of information which can be obtained. The data is analyzed in terms of the frequency dependence of the complex permittivity ε*, specific conductivity σ(ohm-1 cm-1), and the relaxation time τ, parameters which are characteristic of the cure state of the material and independent of the size of the sample. Dynamic dielectric measurements have been used to monitor polymer processing in UDEL-P1700, LARC-160, polyphenyl quinoxaline (PPQ), and Epon 828 cured with Agent U. Dynamic dielectric measurements have been correlated with viscosity for the polysulfone thermoplastic UDEL-P1700 and with viscosity and ultrasonic measurements on the DGEBA type epoxy Epon 828 cured with Agent U. The experimental results suggest that when ionic processes dominate the dielectric response, the intensive property σ is a good monitor of the resin's viscosity. The results show that the dielectric relaxation time τ can be used to monitor the state of the system and the extent and rate of the reaction. Solvent evolution can also be easily observed.
Additional Material:
16 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pen.760260503
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