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  • 1985-1989  (2)
  • Chemistry  (2)
  • Alien limb
  • Antigen-presenting cells
  • Rat (Long Evans)
  • Sciatic nerve, rat
  • 1
    Electronic Resource
    Electronic Resource
    Liquid crystal polymers. IX. Copolyesters of trans-4,4′-stilbenedicarboxylic acid, 1,4-butanediol, and aromatic dicarboxylic acidsPresented in part at the IUPAC International Symposium on Noncrystalline Order in Polymers, May 27-30, 1985, Naples, Italy. (1988)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 26 (1988), S. 835-847 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Copolyesters of trans-4,4-stilbenedicarboxylic acid (SDA), terephthalic acid, and 1,4-butanediol exhibit thermotropic liquid crystallinity if at least 40 mol % SDA is present (acids total 100 mol %); SDA/2,6-naphthalenedicarboxylic acid/1,4-butanediol copolyesters are liquid crystalline if at least 30 mol % SDA is present. The effects of SDA content on the thermal, rheological, plastic, and fiber properties of the copolyesters were determined. The SDA component increases the relaxation times of the polymers and enables injection-molded plastics and melt-spun fibers to have significantly increased tensile strength and stiffness.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1988.080260313
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Liquid crystal polymers. VIII. Liquid crystalline polyesters of trans-4,4′-stilbenedicarboxylic acid and 1,3-propanediol (1987)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 575-579 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In our recent overview of liquid crystalline polyesters of trans-4,4′-stilbenedicarboxylic acid (SDA) and aliphatic glycols,1 we reported that “… the 1,3-propanediol polyester did not exhibit thermotropic liquid crystallinity (no stir opalescence or DSC endotherm above Tm), perhaps because of the relatively high Tm (303°C) for a polymer of a glycol having an odd number of carbon atoms.” We now have studied the melting characteristics of another sample of this polymer more carefully and have concluded that it does exhibit a liquid crystalline mesophase over a very narrow temperature range. In this Note we give the thermal properties of this polymer and the thermal and mechanical properties of an SDA/1,3-propanediol copolyester which we also injection molded. These properties are compared and contrasted with those of the similar polyester and copolyester prepared with 1,4-butanediol instead of 1,3-propanediol.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1987.080250211
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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