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  • 1
    Electronic Resource
    Electronic Resource
    Microemulsions studies: Correlation between viscosity, electrical conductivity and electrochemical and fluorescent probe measurements (1986)
    Springer
    Colloid & polymer science 264 (1986), S. 896-902 
    Details
    ISSN: 1435-1536
    Keywords: Microemulsions ; viscosity ; electrical conductivity ; electrochemical and fluorescent probes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Microemulsion systems involving brine and dodecane, and stabilized by sodium dodecylsulfate and both pentanol and heptanol have been investigated. Results of various experiments including conductivity and viscosity measurements, electrochemical diffusion coefficients and fluorescent probe studies have been gathered and compared in order to gain additional understanding of the microemulsion structure. The diffusion coefficients of hydrophilic hydroquinone and hydrophobic ferrocene obtained from the Levich equation at the rotating disc electrode, vary as the self-diffusion coefficients of water and dodecane, respectively; the results are consistent with those obtained by other workers from tracer or NMR self-diffusion studies. The fluorescence analysis of the polarity sensed by pyrene and the microviscosity felt by dipyrenylpropane suggests that the progressive addition of pentanol and dodecane to SDS micelles leads to solubilizate the probes more in the droplet interior where they experience a more hydrophobic environment. The systematic study of the two microemulsion systems provides insight into the microscopic properties of the oil domains in which the fluorescent probes are assumed to be located. In the system stabilized by n-heptanol as cosurfactant, the microviscosity sensed by P(CH2)3P is shown to be much lower than the bulk viscosity of the microemulsion. All the results evidence the well-known structural transitions: water continuous, bicontinuous and oil continuous in the single monophasic area of the brine/ SDS/n-pentanol/dodecane system; premicellar aggregates and water swollen micelles in the W/O area of the brine/SDS/n-heptanol/dodecane system.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01410641
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Microemulsion structure in the lenticular monophasic areas of brine/SDS/pentanol/dodecane or hexane systems: electrochemical and fluorescent studies (1987)
    Springer
    Colloid & polymer science 265 (1987), S. 45-51 
    Details
    ISSN: 1435-1536
    Keywords: Microemulsions ; viscosity ; conductivity ; electrochemical and fluorescent probes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The properties of pseudo-ternary systems involving brine, sodium dodecylsulfate (SDS), pentanol and dodecane or hexane have been investigated. When the hydrocarbon is dodecane, the microemulsion system includes in addition to the main monophasic area a small lens inserted in an oil-rich zone. With hexane, the microemulsion domain splits into two parts, one of which consists of a narrow scythe-blade shaped area which spreads from the water top up to compositions very rich in hydrocarbon. The properties of these uncommon microemulsions were compared with those of microemulsions belonging to the main monophasic area in order to gain additional understanding of their structure. Results of experiments including electrical conductivity and viscosity measurements, electrochemical and fluorescent probe studies lead to the following conclusions: Microemulsions of the small lens of the brine/SDS/pentanol/dodecane system exhibit properties which are reminiscent of structures with at once water and oil countinuous phases. Microemulsions of the lenticular area of the brine/SDS/pentanol/ hexane system seem to undergo the same structural transitions as microemulsions of systems which present a single monophasic area: water-continuous, bicontinuous and oilcontinuous structures.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01422663
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Effectiveness of linear bifurcation analysis for predicting the nonlinear stability limits of structures (1986)
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 23 (1986), S. 831-846 
    Details
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: As an effort to predict effectively the actual collapse load of a structure, a series of numerical studies on the stability of shell structures are made. The difference in formulation between the two types of linear buckling loads, the classical and the fully linearized, is first demonstrated. Their correlations with respect to the actual stability limit of the structure are compared, and finally the two types of critical load approximations are obtained at various stages of a nonlinear analysis to study the pattern of convergence to the actual collapse load. It is found that the fully linearized buckling analysis, when combined with nonlinear analysis, can serve as a useful tool for prediction of the stability limit of a structure. While for most types of structures the approximation is within engineering accuracy, the rate of convergence of the extrapolated critical load also gives some insight to the accuracy of the approximation.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/nme.1620230506
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    Paper (German National Licenses)
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