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  • 1985-1989  (2)
  • Chemistry  (1)
  • Time-temperature superposition  (1)
  • CO laser
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 26 (1987), S. 499-507 
    ISSN: 1435-1528
    Keywords: Time-temperature superposition ; extrusion swell ; Péclet number
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract A pseudo-time integral scheme based on a finite streamline element method is developed to combine variable temperature with viscoelasticity. A specific KBKZ integral model for isothermal flow is transformed to its non-isothermal version by introducing a pseudo-time and applying the Morland-Lee hypothesis. The coupling between momentum and energy equations is through the time-temperature shifting factor by which the pseudo-time is defined. The observer time and the pseudo-time are simultaneously calculated when tracing the strain history for the stress calculation in a non-homogeneous temperature field. Using this scheme, a full non-isothermal numerical simulation of some IUPAC extrusion experiments is carried out. Results show that while the temperature distribution near the die exit plane is an important factor controlling extrudate swell, either self-heating inside the die tube or external cooling on the free surface dominantly determines the temperature distribution near the die exit when the wall temperature is kept constant, depending on whether the Péclet number is large or small. The hot layer effect predicted by the inelastic swell mechanism is confirmed and well illustrated by the computation. Calculations with reasonable thermal boundary conditions further convince us that the isothermal assumption in our earlier numerical simulation is a good approximation in this particular case.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 25 (1985), S. 620-629 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper extends Petrie's work on film-blowing to cover viscoelastic non-isothermal flow for both the convected Maxwell and the Leonov models. Good agreement with experimental data is shown for the former. The calculations are highly unstable, however, and it is difficult to obtain convergence with arbitrary values of the film-blowing parameters. The general effect of viscoelasticity is to stiffen the film and restrain the increase in bubble diameter. There is some difference between bubble shapes generated using the Maxwell and Leonov constitutive models but the temperature variation of properties is seen as the dominant effect, The Leonov model tends not to be stiff enough in its response to the present flow, which is purely extensional and good agreement with experiment was not obtained. For the Maxwell model the relevant mean relaxation time must be used for good agreement between experiment and calculation.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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