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  • 1
    Electronic Resource
    Electronic Resource
    Electroinitiated polymerization of halophenols: Electroinitiation potential-lumo relations (1988)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 26 (1988), S. 2485-2498 
    Details
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Electroinitiated polymerizations can be carried out by direct electron transfer via constant potential electrolysis.1-3 In doing so, the anodic (Ep, a) and the cathodic (Ep, c) potentials of the monomers must be measured by cyclic voltammetry. The cathodic peak potentials of halophenols were measured on Pt0 electrode versus Ag0/Ag+ in acetonitrile.Electroinitiated polymerization of bis(pyridine), bis(4-chloro-2,6-dibromophenoxide) copper (II) complex was studied in dimethylformamide-tetrabutylammonium fluoroborate by direct electron transfer from the cathode. Poly(phenylene oxides) obtained from the anolyte revealed that the monomer undergoes 1,2 as well as 1,4 addition reactions.Lowest unoccupied molecular orbital energies of the monomers were calculated by Hückel molecular orbital theory. The experimental Ep, c values were correlated to theoretical LUMO energies and electron densities using a multivariable linear regression model.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1988.090261207
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  • 2
    Electronic Resource
    Electronic Resource
    Infrared spectra of acrylonitrile grafted jute fibers (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 38 (1989), S. 1951-1955 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1989.070381016
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  • 3
    Electronic Resource
    Electronic Resource
    Acetylacetone complexes of tetravalent molybdenum (1989)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 570 (1989), S. 159-166 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Acetylacetonat-Komplexe des vierwertigen MolybdänsEinige neue Komplexe des vierwertigen Molybdäns mit Acetylaceton werden dargestellt, wobei sich zwei Reihen von Komplexen mit unterschiedlichen koordinativen Bindungen für Acetylaceton ergeben. Alle Verbindungen werden durch Elementaranalyse, spektroskopische Daten, magnetische und Leitfähigkeits-Messungen charakterisiert.
    Notes: Some new complexes of tetravalent molybdenum containing acetylacetone have been synthesized by the reaction of acetylacetone with hydrated molybdenum(IV) oxide. Two series of complexes having varied coordination linkages for acetylacetone have been isolated under appropriate conditions. All the compounds were characterized through their elemental analyses, spectral data, magnetic moment and conductance measurement.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19895700117
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  • 4
    Electronic Resource
    Electronic Resource
    Nitrosyl rhenium complexes: Syntheses, properties, and structures of acetylacetonato derivatives (1987)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 548 (1987), S. 217-224 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Nitrosyl-Rhenium-Komplexe: Darstellung, Eigenschaften und Struktur von Acetylacetonato-DerivatenEinige neue Rhenium-Komplexe, wie [Re(NO)(acac)2(Cl)H2O] und Re(NO)(acac)3(acacH)(H2O)2 wurden durch Umsatz von Re(NO)Cl3 · H2O bzw. Re(NO)(OH)3 · H2O mit Acetylaceton dargestellt. Ferner wird die Darstellung von [Re(NO)(py)(acac)2(Cl) · H2O], [Re(NO)(acac)(OH)(Cl) · H2O], [Re2(NO)2(acacH)3(acac)2 · Cl4], [Re(NO)(acac)2(OH) · H2O] · 2 H2O angegeben. Die Komplexe werden durch Elementaranalyse, spektroskopische, magnetische und Leitfähigkeitsdaten charakterisiert.
    Notes: Some new complexes of rhenium containing monocoordinating acetylacetone viz. [Re(NO)(acac)2(Cl)H2O], Re(NO)(acac)3(acacH)(H2O)2 have been synthesized by reacting acetylacetone with either Re(NO)Cl3 · H2O or Re(NO)(OH)3 · H2O. The preparation of [Re(NO)(py)(acac)2(Cl) · H2O], [Re(NO)(acac)(OH)(Cl) · H2O], [Re2(NO)2(acacH)3(acac)2 · Cl4], [Re(NO)(acac)2(OH) · H2O] · 2 H2O have also been described. These complexes were characterized through their elemental analyses, u.v., vis, i.r., 1Hn.m.r., magnetic, and conductance data.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19875480524
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  • 5
    Electronic Resource
    Electronic Resource
    Oxalato and Chlorooxalato Derivatives of MoIV (1985)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 524 (1985), S. 201-207 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Oxalato- und Chlorooxalato-Komplexe von MoIVEs wurden die freie Säure Mo(C2O4H)(OH)3H2O und ihre K+-, NH4+- und Pb2+-Salze dargestellt. Aus diesen Verbindungen wurden auch einige Chloro-oxalato-Komplexe hergestellt. Alle Verbindungen wurden chemisch und physicochemisch charakterisiert, und es werden Vorschläge für ihre Strukturen gemacht.
    Notes: A free acid Mo(C2O4H)(OH)3(H2O) has been prepared. The corresponding K+, NH4+ and Pb2+ salts have been synthesized. Starting from this, some chloro-oxalato derivatives were prepared. All the compounds are characterised by chemical and physico-chemical studies and their structures are proposed.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19855240526
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  • 6
    Electronic Resource
    Electronic Resource
    Nitrosyl Rhenium Complexes: Thiocyanato Derivatives (1985)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 526 (1985), S. 179-185 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Rhenium-Nitrosyl-Komplexe: Thiocyanato-DerivateSchmelzen von K2[Re(NO)Cl5] mit KSCN ergibt [Re(NO)(SCN)5]2-, das als freie Säure bzw. in Form der K+-, Na+-, NMe4+-, Pb2+-, Hg2+-, phenH+- und dipyH+-Salze isoliert werden kann. Eine Verbindung mit der Zusammensetzung Hg2[Re(NO)(SCN)7] wurde ebenfalls dargestellt. [Re(NO)Cl(SCN)4]2- wurde bei der Reaktion von H2[Re(NO)(SCN)5] mit HCl in wäßrigem Medium erhalten und als NMe4+-Salz isoliert. In wäßrigem Medium reagiert Re(NO)Cl3 mit KSCN unter Bildung von [Re(NO)Cl2(SCN)3]2-, das als phenH+- und dipyH+-Salz isoliert wurde. Die Komplexe wurden durch Elementaranalyse, spektroskopisch (UV-VIS, IR), magnetisch und durch Leitfähigkeitsmessungen charakterisiert. Strukturen für die Verbindungen werden vorgeschlagen.
    Notes: Fusion of K2[Re(NO)Cl5] with KSCN produces the ion [Re(NO)(SCN)5]2- which has been isolated as free acid and K+, Na+, NMe4+, Pb2+, Hg2+, phen H+ and dipyH+ salts. A salt of composition Hg2[Re(NO)(SCN)7] has also been prepared. The species [Re(NO)Cl(SCN)4]2- has been obtained from the reaction of H2[Re(NO)(SCN)5] with HCl in aqueous medium and its NMe4+ salt has been isolated. Hydrated Re(NO)Cl3 reacts with KSCN in aqueous medium to produce the ion [Re(NO)Cl2(SCN)3]2- which has been isolated as its phenH+ and dipyH+ salts. The complexes have been characterized through elemental analyses, spectral (u.v., vis., i.r.) properties, magnetic and conductance data. The structures of all those compounds have been proposed.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19855260722
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