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  • 1985-1989  (3)
  • Chemical Engineering  (3)
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1728-1734 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pulse gas chromatography experiments at ambient pressure are often limited by an overwhelming contribution of axial dispersion to the observed variance and the inability to obtain a quantitative correction for this factor. Theoretically, the axial dispersion contribution can be reduced and at the same time the contribution due to particle diffusion can be enhanced by operating at elevated pressures. Our experiments on methane/helium diffusion in 0.32-cm-diameter commercial catalyst particles confirm this, and a new means of accounting for axial dispersion is demonstrated.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1750-1753 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1848-1857 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analysis of gas chromatography pulse dispersion data for the system n-butane/zeolite NaY is presented. The data were analyzed in terms of two models, an intracrystalline diffusion limiting model and a surface barrier model. Both models provided acceptable fits to the pulse dispersion data; however, the temperature dependence of the apparent mass transport parameters strongly suggests that a surface barrier is responsible for the observed transport resistance. The Henry's law constants were independent of choice of model and the isosteric heat of sorption was consistent with literature values.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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