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  • 1985-1989  (2)
  • Chemically bonded phases  (1)
  • Olefinic π-complexes  (1)
  • 1
    Digitale Medien
    Digitale Medien
    GC investigation of olefins with chemically bonded gamma-mercaptopropylsilane-copper(II) complexes (1987)
    Springer
    Chromatographia 23 (1987), S. 423-426 
    Details
    ISSN: 1612-1112
    Schlagwort(e): Gas chromatography ; Complexation ; Mercaptosilane chemically bonded phase ; Transition metal complexes ; Olefinic π-complexes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary A column packing containing thiol groups chemically bonded to the silica surface was synthesized. The thiol functional groups were used as ligands capable of forming stable complexes with Cu(II). The prepared material was characterized by gas chromatography using unsaturated linear and branched hydrocarbons as well as cyclic and aromatic hydrocarbons. The occurrence of specific metal—olefin interactions resulting from the formation of π-complexes during the chromatographic process was observed.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF02311818
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Investigation of interactions between chloroderivatives of alkanes and alkenes and chemically bonded transition metal complexes by gas chromatography (1987)
    Springer
    Chromatographia 23 (1987), S. 261-264 
    Details
    ISSN: 1612-1112
    Schlagwort(e): Gas chromatography ; Chemically bonded phases ; Specific interactions ; Chloroderivatives of alkanes and alkenes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary Interactions of Cu(II) complexes chemically bonded to the surface of silica with chloro-derivatives of alkanes and alkenes were investigated. It was found that chlorine as a substituent exerts a considerable influence on the retention of the individual chloro-derivatives. In the case of chloroalkenes this influence is negative while in the case of chloroalkanes it is positive. The magnitude of the observed effect depends on the number of substituents and on the way of their distribution within the molecule.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF02311776
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
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